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4544239270
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note
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-3 for Z = 8.
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16
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4544316635
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note
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1H NMR spectroscopy showed that signals assignable to a "YEt" species were also present.
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4544388488
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-3 for Z = 4. Data were collected at. 123 K on a Nonius Kappa-CCD system. The structure was solved by Patterson methods, and least-square refinement of the model based on 6359 (all data) and 5491 reflections (I> 2.0σ(1)) converged to a final wR2 = 0.0654 and R1 = 0.0263, respectively. All hydrogen atoms of the methyl groups-bonded to aluminum were found in the difference Fourier maps and allowed to refine freely. All of the other hydrogen atoms were placed in calculated positions (riding model). CCDC-226742 (9a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/ conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or deposit@ ccdc.cam.ac.uk).
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36
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0000294593
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