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a) CCDC-268899, -268900, -268901, and -268902 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif;
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33
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28044457834
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4] in THF (see Supporting Information).
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34
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28044471132
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2, which contains a ring-opened THF group according to an X-ray crystallographic determination. For similar reactions, see ref. [9b];
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5] pyridine (see Supporting Information).
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28044442211
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note
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3 did not lead to 1,3-diene polymerization.
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41
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28044432922
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note
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3 (probably needed as scavenger for THF). See Supporting Information for experimental details.
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28044431765
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a) Up to three growing chains per metal center have been reported for neutral allyl rare-earth complexes, see refs. [3b] and [13b];
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note
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4] does not catalyze the polymerization of isoprene. The yellow color of the reaction mixture indicates the formation of an allylic species as a result of CH activation of toluene;
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45
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28044457833
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a) Polymerization-active contact ion pairs are unknown in lanthanide chemistry, the presence of non- or weakly coordinating anions is generally regarded as a decisive factor in the polymerization activity, see refs. [16b, c];
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28044462587
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see ref. [18e]
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6-coordination of the solvent to cationic scandium complexes, see ref. [18e];
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28044444488
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see ref. [18b]
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a) In cationic alkylchromium complexes, similar reactivity differences between complexes with protonated and perfluorinated counterions are seen, see ref. [18b];
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61
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13644253045
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28044436220
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note
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8]toluene by NMR spectroscopy were unsuccessful, because of the formation of easily decomposable, oily, two-phase systems as a result of the relatively high concentrations required;
-
-
-
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63
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28044438857
-
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see ref. [2b]
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4], for which the resulting cationic complex was examined by X-ray crystallography, see ref. [2b].
-
-
-
|