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To enable polymerization reactions in aliphatic hydrocarbons such as hexane, cyclohexane, and heptane industrially applied catalytic systems are based on Nd(III) precursors with branched or cyclic aliphatic groups that contain eight or more carbon atoms. For example, there are neodymium versatate (isomeric mixture of α,α-disubstituted decanoic carboxylates), neodymium naphthenate (isomeric mixture of substituted cyclopentyl and cyclohexyl carboxylates), and neodymium bis(2-ethylhexyl)phosphate.
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4)] via aryloxide → alkyl exchange; see ref 13.
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32
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33750308079
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note
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int = 0.084) [7694 observed reflections (I > 2σ(I)]. R1 = 0.0557, wR2 = 0.0795, GooF = 0.977. All hydrogen atoms except those of the bridging methyl groups C1 and C2 were placed in idealized calculated positions and included in the structure factor calculation but not refined (riding model). The hydrogen atoms at C1 and C2 were located in the difference Fourier map and refined freely.
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