A new family of monocyclopentadienyl organoscandium bis-alkyls supported by a bulky trialkylphosphine oxide ancillary

Canadian Journal of Chemistry

Volumn 82, Issue 2, 2004, Pages 162-165

  Henderson, Lee D ^a   MacInnis, Glen D ^a   Piers, Warren E ^a   Parvez, Masood ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

Cationic complexes; Olefin polymerization; Organoscandium compounds

Indexed keywords

ACTIVATION ANALYSIS; CRYSTAL STRUCTURE; DERIVATIVES; ETHYLENE; MONOMERS; PHOSPHORUS COMPOUNDS; POLYMERIZATION; SCANDIUM COMPOUNDS;

MONOCYCLOPENTADIENYL DICHLORIDE; OLIGOMERIC COMPOUNDS; PHOSPHENE OXIDE LIGANDS; THREE-LEGGED PIANO STOOL GEOMETRY;

OLIGOMERS;

ETHYLENE; LITHIUM DERIVATIVE; MONOCYCLOPENTADIENYL SCANDIUM DICHLORIDE; OLIGOMER; ORGANOMETALLIC COMPOUND; PHOSPHINE OXIDE DERIVATIVE; SCANDIUM; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION; CRYSTAL STRUCTURE; OLIGOMERIZATION; ORGANIC CHEMISTRY; POLYMERIZATION; REACTION ANALYSIS;

EID: 2342510952     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-157     Document Type: Article

References (34)

1. D.J.H. Emslie and W.E. Piers. Coord. Chem. Rev. 233-234, 129 (2002).
2. L. Bourget-Merle, M.F. Lappert, and J.R. Severn. Chem. Rev. 102, 3031 (2002).
3. P.G. Hayes, L.W.M. Lee, L.K. Knight, W.E. Piers, M. Parvez, M.R.J. Elsegood, W. Clegg, and R. McDonald. Organometallics, 20, 2533 (2001).
4. (a) L.W.M. Lee, W.E. Piers, M.RJ. Elsegood, W. Clegg, and M. Parvez. Organometallics, 18, 2947 (1999);
5. (b) P.G. Hayes, W.E. Piers, and R. McDonald. J. Am. Chem. Soc. 124, 2132 (2002);
6. (c) P.G. Hayes, W.E. Piers, and M. Parvez. J. Am. Chem. Soc. 125, 5622 (2003).
7. (a) G.C. Welch, P.G. Hayes, D.J.H. Emslie, C.L. Noack, W.E. Piers, and M. Parvez. Organometallics, 22, 1577 (2003).
8. (a) A.M. Neculai, H.W. Roesky, D. Neculai, and J. Magull. Organometallics, 20, 5501 (2001);
9. (b) A.M. Neculai, D. Neculai, H.W. Roesky, J. Magull, M. Baldus, O. Andreonesi, and M. Jansen. Organometallics, 21, 2590 (2002).
10. (a) D.W. Stephan, J.C. Stewart, F. Guerin, S. Courtenay, J. Kickham, E. Hollink, C. Beddie, A. Hoskin, T. Graham, P. Wei, R.E.v. H. Spence, W. Xu, L. Koch, X. Gao, and D.G. Harrison. Organometallics, 22, 1937 (2003);
11. (b) N. Yue, E. Hollink, F. Guerin, and D.W. Stephan. Organometallics, 20, 4424 (2001);
12. (c) F. Guerin, J.C. Stewart, C. Beddie, and D.W. Stephan. Organometallics, 19, 2994 (2000);
13. (d) D.W. Stephan, J.C. Stewart, F. Guerin, R.E.v.H. Spence, W. Xu, and D.G. Harrison. Organometallics, 18, 1116 (1999);
14. (e) D.W. Stephan, F. Guerin, R.E.v. H. Spence, L. Koch, X. Gao, S.J. Brown, J.W. Swabey, Q. Wang, W. Xu, P. Zoricak, and D.G. Harrison. Organometallics, 18, 2046 (1999).
15. (a) K. Dehnicke, S. Anfang, K. Harms, F. Weller, O. Borgmeier, H. Lueken, and H. Schilder. Z. Anorg. Allg. Chem. 624, 159 (1998);
16. (b) M.J. Sarsfield, M. Said, M. Thornton-Pett, L.A. Gerrad, and M. Bochmann. J. Chem. Soc. Dalton Trans. 822 (2001);
17. (c) K. Dehnicke, M. Krieger, and W. Massa. Coord. Chem. Rev. 182, 19 (1999).
18. T.V. Lubben, P.T. Wolczanski, and G.D. Van Duyne. Organometallics, 3, 977 (1984).
19. W.E. Piers, E.E. Bunel, and J.E. Bercaw. J. Organomet. Chem. 407, 51 (1991).
20. H. Schmidbaur and G. Blaschke. Z. Naturforsch. 33B, 1556 (1978).
21. (a) L. Deakin, W. Levanson, M.C. Popham, G. Reid, and M. Webster. J. Chem. Soc. Dalton Trans. 2439 (2000);
22. (b) J. Fawcett, A.W.G. Platt, and D.R. Russell. Polyhedron, 21, 287 (2002);
23. (c) N.J. Hill, W. Levason, M.C. Popham, G. Reid, and M. Webster. Polyhedron, 21, 1579 (2002).
24. (a) P.B. Hitchcock, M.F. Lappert, and A. Singh. J. Chem. Soc. Chem. Commun. 1499 (1983);
25. (b) G.B. Deacon, P.E. Fanwick, A. Gitlits, I.P. Rothwell, B.W. Skelton, and A.H. White. Eur. J. Inorg. Chem. 1505 (2001).
26. (a) J.L. Atwood and K.D. Smith. J. Chem. Soc. Dalton Trans. 921 (1974);
27. (b) B. Campion and T.D. Tilley. Organometallics, 12, 2584 (1993).
28. J. Sandström. Dynamic NMR spectroscopy. Academic Press, Toronto. 1982. pp. 93-97.
29. C.L. Perrin and T.J. Dwyer. Chem. Rev. 90, 935 (1990).
30. (a) M.A. Beckett, D.S. Brassington, S.J. Coles, and M.B. Hursthouse. Inorg. Chem. Commun. 3, 530 (2000);
31. (b) M.A. Beckett, D.S. Brassington, M.E. Light, and M.B. Hursthouse. J. Chem. Soc. Dalton Trans. 1768 (2001).
32. A.D. Horton and J. de With. Organometallics, 16, 5424 (1997).
33. E.Y.-X. Chen and T.J. Marks. Chem. Rev. 100, 1391 (2000).
34. M.E. Thompson, S.M. Baxter, A.R. Bulls, B.J. Burger, M.C. Nolan, B.D. Santarsiero, W.P. Schaefer, and J.E. Bercaw. J. Am. Chem. Soc. 109, 203 (1987).