Mixed aluminum-magnesium-rare earth allyl catalysts for controlled isoprene polymerization: Modulation of stereocontrol

Macromolecular Rapid Communications

Volumn 27, Issue 5, 2006, Pages 338-343

  Ajellal, Noureddine ^a   Furlan, Luciano ^b   Thomas, Christophe M ^a   Casagrande Jr , Osvaldo L ^b   Carpentier, Jean François ^a  

^a UMR 6509 Organometalliques et Catalyse Chimie et Electrochimie Moleculaires   (France)

^b FEDERAL UNIVERSITY OF RIO GRANDE DO SUL   (Brazil)

Author keywords

Isoprene; Microstructure; Polydienes; Rare earth catalysts

Indexed keywords

ALUMINUM; CATALYSTS; MAGNESIUM; MICROSTRUCTURE; MOLECULAR WEIGHT; POLYMERIZATION;

ISOPRENE; POLYDIENES; RARE EARTH CATALYSTS; STEREOCONTROL;

RARE EARTHS;

EID: 33750289879     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.200500775     Document Type: Article

References (52)

1. For reviews, see: [1a] L. Porri, A. Giarrusso, in: "Comprehensive Polymer Science", G. C. Eastmond, A. Ledwith, S. Russo, P. Sigwalt, Eds., Pergamon Press, Oxford, UK 1989, Vol. 4, pp. 53-108;
2. [1b] R. Taube, G. Sylvester, in: "Applied Homogeneous Catalysis", B. Cornus, W. A. Herrmann, Eds., VCH, Weinheim 1996, Vol. 1, pp. 280-318.
3. [2a] S. Kaita, Z. Hou, Y. Wakatsuki, Macromolecules 1999, 32, 9078;
4. [2b] Z. Hou, S. Kaita, Y. Wakatsuki, Macromolecules2001, 34, 1539;
5. [2c] S. Kaita, Z. Hou, M. Nishiura, Y. Doi, J. Kurazumi, C. A. Horiuchi, Y. Wakatsuki, Macromol. Rapid Commun. 2003, 24, 179;
6. [2d] S. Kaita, Y. Doi, K. Kaneko, A. C. Horiuchi, Y. Wakatsuki, Macromolecules 2004, 37, 5460.
7. [3a] L. Porri, G. Ricci, S. Italia, F. Cabassi, Polym. Commun. 1987, 28, 223;
8. [3b] L. Porri, G. Ricci, A. Giarrusso, N. Shubin, Z. Lu, ACS Symp. Ser. 2000, 749, 15.
9. [4a] W. J. Evans, D. G. Giarikos, J. W. Ziller, Organometallics 2001,20,5751 ;
10. [4b] W. J. Evans, D. G. Giarikos, N. T. Alien, Macromolecules 2003, 36, 4256;
11. [4c] W. J. Evans, T. M. Champagne, D. G. Giarikos, J. W. Ziller, Organometallics 2005, 24, 570 and references therein.
12. [5a] R. Taube, H. Windisch, S. Maiwald, Macromol. Symp. 1995, 89, 393;
13. [5b] S. Maiwald, C. Sommer, G. Muller, R. Taube, Macromol. Chem. Phys. 2002, 203, 1029.
14. [6a] F. Bonnet, M. Visseaux, D. Barbier-Baudry, A. Dormond, Macromolecules 2002, 35, 1143;
15. [6b] F. Bonnet, M. Visseaux, D. Barbier-Baudry, J. Organomet. Chem. 2004, 689, 264.
16. [7a] H. lovu, G. Hubca, E. Simionescu, E. Badea, J. S. Hurst, Eur. Polymer. J. 1997, 33, 811;
17. [7b] C. Boisson, F. Barbotin, R. Spitz, Macromol. Chem. Phys. 1999, 200, 1163;
18. [7c] R. Quirk, A. Keils, K. M. Yunlu, J.-P. Cuif, Polymer 2000, 41, 5903;
19. [7d] G. Kwag, Macromolecules 2002, 35, 4875.
20. [8a] A. Fischbach, F. Perdih, P. Sirsch, W. Scherer, R. Anwander, Organometallics 2002, 22, 4569;
21. [8b] A. Fischbach, M. G. Klimpel, M. Widenmeyer, E. Herdtweck, W. Scherer, R. Anwander, Angew. Chem. Int. Ed. 2004, 43, 2234.
22. S. Mainwald, H. Weissenborn, C. Sommer, G. Müller, R. Taube, J. Organomet. Chem. 2001, 640, 1.
23. [10a] D. Barbier-Baudry, F. Bonnet, B. Domenichini, A. Dormond, M. Visseaux, J. Organomet. Chem. 2002, 647, 167;
24. [10b] F. Bonnet, M. Visseaux, A. Pereira, F. Bouyer, D. Barbier-Baudry, Macromol. Rapid Commun. 2004, 25, 873;
25. [10c] F. Bonnet, M. Visseaux, A. Pereira, D. Barbier-Baudry, Macromolecules 2005, 38, 3162.
26. J. Gromada, L. Le Pichon, F. Leising, A. Mortreux, J.-F. Carpentier, J. Organomet. Chem. 2003, 683, 44.
27. L. Zhang, Y. Luo, Z. Hou, J. Am. Chem. Soc. 2005, 727, 14562 and references therein.
28. [13a] R. Taube, H. Windisch, F. H. Gorlitz, H. Schumann, J. Organomet. Chem. 1993, 445, 85;
29. [13b] R. Taube, H. Windisch, S. Maiwald, H. Hemling, H. Schumann, J. Organomet. Chem. 1996, 513, 49;
30. [13c] R. Taube, H. Windisch, H. Weissenborn, H. Hemling, H. Schumann, J. Organomet. Chem. 1997, 548, 229;
31. [13d] S. Maiwald, R. Taube, H. Hemling, H. Schumann, J. Organomet. Chem. 1998, 552, 195;
32. [13e] R. Taube, H. Windisch, H. Hemling, H. Schumann, J. Organomet. Chem. 1998, 555, 201 ;
33. [13f] R. Taube, S. Maiwald, J. Sieler, J. Organomet. Chem. 2001, 621, 327;
34. [13g] R. Taube, in: " Metalorganic Catalysts for Synthesis and Polymerization", W. Kaminsky, Ed., Springer, Berlin 1999, pp. 531-547.
35. For the use of discrete allyl lanthanide complexes as singlecomponent catalysts for stereospecific polymerization of monomers other than dienes, see: [14a] T. J. Woodman, M. Schormann, D. L. Hughes, M. Bochmann, Organometallics 2003, 22, 3028;
36. [14b] T. J. Woodman, M. Schormann, M. Bochmann, Organometallics 2003, 22, 2938;
37. [14c] T. J. Woodman, M. Schormann, D. L. Hughes, M. Bochmann, Organometallics 2004, 23, 2972;
38. [ 14d] L. F. Sanchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics 2005, 24, 5329;
39. [14e] L. F. Sanchez-Barba, D. L. Hughes, S. M. Humphrey, M. Bochmann, Organometallics 2005, 24, 3792;
40. [14f] E. Kirillov, C. W. Lehmann, A. Razavi, J.-F. Carpentier, J. Am. Chem. Soc. 2004, 126, 12240.
41. W. Wu, M. Chen, P. Zhou, Organometallics 1991,10, 98.
42. Y. Jin, F. Li, F. Pei, F. Wang, Y. Sun, Macromolecules 1994, 27, 4397.
43. S. Arndt, K. Beckerle, P. M. Zeimentz, T. P. Spaniol, J. Okuda, Angew. Chem. Int. Ed. 2005, 44, 1.
44. Recent organolanthanide reviews: [18a] H. Schumann, J. A. Meese-Marktscheffel, L. Esser, Chem. Rev. 1995, 95, 865;
45. [18b] R. Anwander, W. A. Herrmann, Top. Curr. Chem. 1996, 779, 1;
46. [18c] F. T. Edelmann, Top. Curr. Chem. 1996, 179, 247;
47. [18d] R. Anwander, in: "Applied Homogeneous Catalysis with Organometallic Compounds", B. Cornils, W. A. Herrmann, Wiley, Weinheim 1996, Vol. 2, p. 866;
48. [ 18e] R. Anwander, Top. Organomet. Chem. 1999, 2, 1 ;
49. [ 18f] G. A. Molander, E. C. Dowdy, Top. Organomet. Chem. 1999, 2, 119;
50. [18g] S. Arndt, J. Okuda, Chem. Rev. 2002, 102, 1953;
51. [18h] Z. Hou, Y Wakatsuki, Coord. Chem. Rev. 2002, 237, 1;
52. [18i] J. Gromada, J.-F. Carpentier, A. Mortreux, Coord. Chem. Rev. 2004, 248, 397.