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Crystal data for 1: C29.50H15.75F 8IrN7.25, Mr, 815.94, orthorhombic, space group Pbca, T, 150 K, a, 17.7805(3, b, 17.7519(3, c, 35.9198(6) Å, V, 11337.6(3) Å3, Z, 16, μ(MoKα, 4.799 mm -1; 27243 reflections were collected of which 9959 were unique (Rint, 0.1349, final R1[I>2σ(I, 0.0694, wR2(all data, 0.1661. Crystal data for 2: C30H20F8IrN 7O, Mr, 838.73, triclinic, space group P1, T, 150 K, a, 10.8152(3, b, 14.8498(4, c, 20.6391(5) Å, α, 85.0088(15, β, 75.4553(14, γ, 79.6901(14)°, V, 3153.60(14) Å3, Z, 4, μMoKα, 4.318 mm-1;
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