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Volumn 46, Issue 3, 2007, Pages 377-380

[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand

Author keywords

Aldehyde deformylation; Bioinorganic chemistry; Enzyme models; Manganese; O O activation

Indexed keywords

ACTIVATION ANALYSIS; ALDEHYDES; COMPLEXATION; CRYSTAL STRUCTURE; ENZYMES; POSITIVE IONS; REACTION KINETICS;

EID: 33846422707     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200603414     Document Type: Article
Times cited : (119)

References (40)
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    • (2004) Comprehensive Coordination Chemistry II , vol.8
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    • Angew1
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    • R. Tagore, H. Chen, R. H. Crabtree, G. W. Brudvig, J. Am. Chem. Soc. 2006, 128, 9457-9465, and references therein;
    • a) R. Tagore, H. Chen, R. H. Crabtree, G. W. Brudvig, J. Am. Chem. Soc. 2006, 128, 9457-9465, and references therein;
  • 29
    • 33845554369 scopus 로고    scopus 로고
    • Although we have attempted to measure resonance Raman spectra of 1, we failed to observe ν(O-O) and ν(Mn-O2) vibrations when using 413- and 624.8-nm laser excitations. It is worth noting that no Raman vibrations of MnIII-O2 species have been reported yet, but O-O stretching bands have been observed between 890 and 1000 cm-1 in infrared spectra. See reference [8] and M. W. Urban, K. Nakamoto, F. Basolo, Inorg. Chem. 1982, 21, 3406-3408
    • -1 in infrared spectra. See reference [8] and M. W. Urban, K. Nakamoto, F. Basolo, Inorg. Chem. 1982, 21, 3406-3408.
  • 30
    • 33846460262 scopus 로고    scopus 로고
    • 2+ (bpmen = N,N′-dimethyl-N,N′-bis(2- pyridylmethyl)-1,2-diaminoethane), did not show the formation of peroxido manganese(III) complexes under the identical reaction conditions.
    • 2+ (bpmen = N,N′-dimethyl-N,N′-bis(2- pyridylmethyl)-1,2-diaminoethane), did not show the formation of peroxido manganese(III) complexes under the identical reaction conditions.
  • 31
    • 0035935015 scopus 로고    scopus 로고
    • + shows that the four N-methyl groups are located on the same side of the manganese ion and point toward the chloride ligand: C. Bucher, E. Duval, J.-M. Barbe, J.-N. Verpeaux, C. Amatore, R. Guilard, L. Le Pape, J.-M. Latour, S. Dahaoui, C. Lecomte, Inorg. Chem. 2001, 40, 5722-5726.
    • + shows that the four N-methyl groups are located on the same side of the manganese ion and point toward the chloride ligand: C. Bucher, E. Duval, J.-M. Barbe, J.-N. Verpeaux, C. Amatore, R. Guilard, L. Le Pape, J.-M. Latour, S. Dahaoui, C. Lecomte, Inorg. Chem. 2001, 40, 5722-5726.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.