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Although we have attempted to measure resonance Raman spectra of 1, we failed to observe ν(O-O) and ν(Mn-O2) vibrations when using 413- and 624.8-nm laser excitations. It is worth noting that no Raman vibrations of MnIII-O2 species have been reported yet, but O-O stretching bands have been observed between 890 and 1000 cm-1 in infrared spectra. See reference [8] and M. W. Urban, K. Nakamoto, F. Basolo, Inorg. Chem. 1982, 21, 3406-3408
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2+ (bpmen = N,N′-dimethyl-N,N′-bis(2- pyridylmethyl)-1,2-diaminoethane), did not show the formation of peroxido manganese(III) complexes under the identical reaction conditions.
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2+ (bpmen = N,N′-dimethyl-N,N′-bis(2- pyridylmethyl)-1,2-diaminoethane), did not show the formation of peroxido manganese(III) complexes under the identical reaction conditions.
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