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Volumn 125, Issue 52, 2003, Pages 16160-16161

An Iron-Peroxo Porphyrin Complex: New Synthesis and Reactivity Toward a Cu(II) Complex Giving a Heme-Peroxo-Copper Adduct

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; DRUG DERIVATIVE; HEME; IRON; PORPHYRIN DERIVATIVE;

EID: 0347695004     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036632d     Document Type: Article
Times cited : (41)

References (31)
  • 3
    • 0348104552 scopus 로고    scopus 로고
    • note
    • 8TPP = tetrakis-(2,6-difluoro-phenyl)porphyrinate: TPP = tetra(phenyl)porphyrinate; Cp = cyclopentadienyl; TMPA = tris(2-pyridyl-methyl)amine.
  • 5
    • 0346844000 scopus 로고    scopus 로고
    • note
    • - can also be obtained either by electrochemical6 or chemical [aluminum hydride reagent]7 reduction of a porphyrin ferrous dioxygen, or by addition of dioxygen to an iron(I) porphyrin.8
  • 17
    • 0346213414 scopus 로고    scopus 로고
    • note
    • See Supporting Information.
  • 24
    • 0347474632 scopus 로고    scopus 로고
    • note
    • Vibrational spectroscopic characterization of peroxide 3 has been thwarted by its thermal instability (IR) or photodecomposition (resonance Raman).
  • 26
    • 0348104551 scopus 로고    scopus 로고
    • note
    • While we have observed no problems, perchlorate salts are potentially explosive and should be handled with great care.
  • 27
    • 0346213413 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum.
  • 29
    • 0037063563 scopus 로고    scopus 로고
    • Tolman and co-workers report a related methodology, wherein a copper-(1) complex is added to another side-on dioxygen-Cu complex; this leads to a bis-μ-oxo dicopper(III) product. See J. Am. Chem. Soc. 2002, 124, 10660.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 10660
  • 30
    • 0347474633 scopus 로고    scopus 로고
    • note
    • - (ref 230).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.