메뉴 건너뛰기




Volumn 1, Issue 5, 2006, Pages 707-711

Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to α,β-unsaturated ketones

Author keywords

Addition; Catalytic cycles; Diene ligands; Kinetics; Rhodium

Indexed keywords


EID: 33845236732     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200600184     Document Type: Article
Times cited : (53)

References (45)
  • 1
    • 0003445429 scopus 로고    scopus 로고
    • (Eds.: E. N. Jaeobsen, A. Pfaltz, H. Yamamoto), Springer, Heidelberg
    • For reviews, see: a) Comprehensive Asymmetric Catalysis (Eds.: E. N. Jaeobsen, A. Pfaltz, H. Yamamoto), Springer, Heidelberg, 1999;
    • (1999) Comprehensive Asymmetric Catalysis
  • 36
    • 33845242237 scopus 로고    scopus 로고
    • note
    • 3) was used as a precursor of 1; see reference [12].
  • 37
    • 33845253125 scopus 로고    scopus 로고
    • note
    • An excess of boric acid was added to minimize the change in its concentration throughout the reaction.
  • 38
    • 33746248151 scopus 로고    scopus 로고
    • For an expert review, see: D.G. Blackmond, Angew. Chem. 2005, 117, 4374;
    • (2005) Angew. Chem. , vol.117 , pp. 4374
    • Blackmond, D.G.1
  • 43
    • 33845266118 scopus 로고    scopus 로고
    • note
    • For the parameter ["excess"], see reference [17].
  • 44
    • 33845251805 scopus 로고    scopus 로고
    • note
    • total becomes larger (0.65) than 0.5, which was observed for the binap catalyst. The half-order kinetics with respect to the catalyst is reported in references [12] and [18a].
  • 45
    • 0004286747 scopus 로고    scopus 로고
    • Wiley, New York
    • Kinetic modeling of the data to fit the proposed rate expression was carried out with the Excel Solver program. Error analysis of the fits was performed with SlovStat (a statistics program purchased with E. J. Billo, Excel for Chemists, Wiley, New York, 2001).
    • (2001) Excel for Chemists
    • Billo, E.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.