Preparation of C2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids

Journal of Organic Chemistry

Volumn 70, Issue 7, 2005, Pages 2503-2508

  Otomaru, Yusuke ^a   Okamoto, Kazuhiro ^a   Shintani, Ryo ^a   Hayashi, Tamio ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLIC ACIDS; CATALYSIS; CATALYST ACTIVITY; RHODIUM;

CHIRAL DIENE LIGANDS; LINEAR SUBSTRATES; PHENYL GROUPS;

AROMATIC HYDROCARBONS;

ALKADIENE; BORONIC ACID DERIVATIVE; RHODIUM;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL PROCEDURES; CHEMICAL REACTION; ENANTIOSELECTIVITY; REACTION ANALYSIS;

EID: 17044390818     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo047831y     Document Type: Article

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41. 2 as an active catalyst.
42. We have established the catalytic cycle of the rhodium-catalyzed 1,4-addition reactions: see ref 14.