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For examples of rhodium-catalyzed processes, see: a) D. F. Cauble, J. D. Gipson, M. J. Krische, J. Am. Chem. Soc. 2003, 125, 1110;
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24
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21244498076
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note
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Compound 3a is presumably formed through a pathway similar to that reported in ref. [2h].
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25
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6444231736
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a) N. Tokunaga, Y. Otomaru, K. Okamoto, K. Ueyama, R. Shintani, T. Hayashi, J. Am. Chem. Soc. 2004, 126, 13 584;
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17044390818
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b) Y. Otomaru, K. Okamoto, R. Shintani, T. Hayashi, J. Org. Chem. 2005, 70, 2503.
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27
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21244472184
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note
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This conclusion does not necessarily fully explain the low chemoselectivity in the reaction of 1a with phenylboronic acid in the presence of a Rh-bisphosphine catalyst (Table 1).
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