Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: Kinetic studies under synthetically relevant conditions

Journal of the American Chemical Society

Volumn 124, Issue 47, 2002, Pages 14104-14114

  Singh, Utpal K ^a   Strieter, Eric R ^a   Blackmond, Donna G ^b   Buchwald, Stephen L ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF HULL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AMINATION; AMINES; CALORIMETRY; CATALYSIS; MIXTURES;

INDUCTION PERIODS;

REACTION KINETICS;

BROMIDE; BROMOBENZENE; LEAD; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

AMINATION; ANALYTIC METHOD; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; DATA ANALYSIS; PROTON TRANSPORT; REACTION ANALYSIS; STEADY STATE; SYNTHESIS;

EID: 0037184431     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026885r     Document Type: Article

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39. We are grateful to a referee for the suggestion concerning the interaction of base with dba.
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45. -l differs slightly from that found by taking the ratio of the individual values shown in the table because of roundoff error.
46. -1, ref 9).