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Volumn 124, Issue 47, 2002, Pages 14104-14114

Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: Kinetic studies under synthetically relevant conditions

Author keywords

[No Author keywords available]

Indexed keywords

AMINATION; AMINES; CALORIMETRY; CATALYSIS; MIXTURES;

EID: 0037184431     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026885r     Document Type: Article
Times cited : (144)

References (46)
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  • 26
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    • note
    • 0) is different for the two reactions were sufficient to provide a unique solution for the three elementary step rate constants.
  • 28
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    • note
    • 2 carried out at [1] < 0.1 M were not in agreement with those carried out at substrate concentrations of 0.5-4 M. They invoked a change in mechanism to rationalize these results.
  • 39
    • 84926229848 scopus 로고    scopus 로고
    • note
    • We are grateful to a referee for the suggestion concerning the interaction of base with dba.
  • 41
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    • note
    • 2 to form a three-coordinate Pd species that undergoes oxidative addition has previously been suggested (refs 2a and 9).
  • 42
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    • note
    • 31P NMR could not be determined unambiguously, this result indicates that the amine interacts with the precatalyst.
  • 44
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    • note
    • The values given in Table 1 assume that all of the Pd is present as active catalyst. The relative trends in rate constants hold regardless of the actual concentration of active Pd, although the absolute values will be normalized by the fraction of Pd present in the cycle.
  • 45
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    • note
    • -l differs slightly from that found by taking the ratio of the individual values shown in the table because of roundoff error.
  • 46
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    • note
    • -1, ref 9).


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