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Volumn 128, Issue 43, 2006, Pages 14093-14102

High fidelity kinetic self-sorting in multi-component systems based on guests with multiple binding epitopes

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); POSITIVE IONS; PROTEINS; REACTION KINETICS; SUPRAMOLECULAR CHEMISTRY;

EID: 33750447985     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja063390j     Document Type: Article
Times cited : (187)

References (61)
  • 1
    • 0000129078 scopus 로고
    • The concept of kinetic versus thermodynamic control is well developed in covalent bond-forming reactions. Curtin, D. Y. Rec. Chem. Prog. 1954, 15, 111-128;
    • (1954) Rec. Chem. Prog. , vol.15 , pp. 111-128
    • Curtin, D.Y.1
  • 18
    • 0037079054 scopus 로고    scopus 로고
    • Kitano, H. Nature 2002, 420, 206-210;
    • (2002) Nature , vol.420 , pp. 206-210
    • Kitano, H.1
  • 45
    • 33750466782 scopus 로고    scopus 로고
    • note
    • 1H NMR (e.g. fidelity of kinetic and thermodynamic sorting), (2) use of GEPASI to rationalize the outcome with guessed (estimated) kinetic and thermodynamic values as inputs and thereby inform chemical intuition, and (3) the use of these insights to guide the next round of iteration. We investigated approximately 20 pairs of guests-mainly derivatives of adamantylamines and cyclohexylamines- before discovering the system described in this paper. The discovery process took approximately 3 months including time for synthesis of the requisite two-faced guests.
  • 47
    • 33750482467 scopus 로고    scopus 로고
    • GEPASI can be downloaded free-of-charge at http://www.gepasi.org;
  • 60
    • 33750436812 scopus 로고    scopus 로고
    • note
    • 2O molecules are displaced by coordination with O-atoms of the carbonyl-lined portals of CB[n].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.