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Volumn 126, Issue 8, 2004, Pages 2288-2289

Can Multivalency Be Expressed Kinetically? The Answer Is Yes

Author keywords

[No Author keywords available]

Indexed keywords

CROWN ETHER DERIVATIVE; PYRIDINIUM DERIVATIVE;

EID: 1542345324     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0395285     Document Type: Article
Times cited : (84)

References (37)
  • 19
    • 1542379733 scopus 로고    scopus 로고
    • note
    • 6 after anion exchange. For further details, see Supporting Information.
  • 29
    • 1542289752 scopus 로고    scopus 로고
    • note
    • 6 is kinetically stable at 253 K.
  • 30
    • 0004041546 scopus 로고
    • McGraw-Hill: New York; Chapter 3
    • The experimental data points were fitted to a model for the reversible first-order reaction by nonlinear square fitting using SigmaPlot 8.0 software. For further details, see: Espenson, J. H. Chemical Kinetics and Reaction Mechanisms; McGraw-Hill: New York, 1995; Chapter 3.
    • (1995) Chemical Kinetics and Reaction Mechanisms
    • Espenson, J.H.1
  • 31
    • 0030901130 scopus 로고    scopus 로고
    • For some further examples of strict self-assembly, see: (a) Zimmerman, S. C. Science 1997, 276, 543-544.
    • (1997) Science , vol.276 , pp. 543-544
    • Zimmerman, S.C.1
  • 36
    • 1542379735 scopus 로고    scopus 로고
    • note
    • 6+ compared with its trisammonium-based analogue.
  • 37
    • 0037032301 scopus 로고    scopus 로고
    • Indeed, there are instances in nature, e.g., a recent study carried out on the high-avidity, reversible low-affinity multivalent interactions of the lectin XL35 with the jelly coat proteins surrounding oocytes in Xenopus laevis shows that they require a very long time to reach equilibrium, so long in fact that the partners do not attain true equilibrium on the timescale of the biological event, namely polyspermy, yet are such that their metastable mode of interaction is probably more than enough to guarantee an insurmountable physical block to polyspermy. See: Arranz-Plaza, E.; Tracy, A. S.; Siriwardena, A.; Pierce, J. M.; Boons, G.-J. J. Am. Chem. Soc. 2002, 124, 13035-13046.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 13035-13046
    • Arranz-Plaza, E.1    Tracy, A.S.2    Siriwardena, A.3    Pierce, J.M.4    Boons, G.-J.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.