Coordination polymerization of dienes, allenes, and methylenecycloalkanes

Advances in Polymer Science

Volumn 171, Issue , 2004, Pages 137-194

  Osakada, Kohtaro ^a   Takeuchi, Daisuke ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Allene; Coordination polymerization; Copolymerization; Diene; Methylenecyclopropane

Indexed keywords

ALKADIENE; ALLENE DERIVATIVE; CYCLOALKANE DERIVATIVE; LANTHANOCENE; METAL COMPLEX; METHYLENECYCLOPROPANE; NICKEL; PALLADIUM; POLYMER; PROPANE; UNCLASSIFIED DRUG;

CATALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; METAL BINDING; POLYMERIZATION; REACTION ANALYSIS; REVIEW;

EID: 9644257457     PISSN: 00653195     EISSN: None     Source Type: Book Series    
DOI: 10.1007/b13016     Document Type: Review

References (252)

1. For reviews on polymerization of dienes: (a) Porri L, Giarrusso A (1989) Conjugated diene polymerization. In: Ledwith A, Russo S, Sigewalt P (eds) Comprehensive polymer science, vol 4, Chap 5. Pergamon, Oxford, p 53;
2. (b) Porri L, Giarrusso A, Ricci G (1991) Prog Polym Sci 16:405;
3. (c) Watanabe H, Masuda T (1997) Diene polymerization. In: Kobayashi S (ed) Catalysis in precision polymerization. Wiley, Chichester, p 55;
4. (d) Tindall D, Pawlow JH, Wagener KB (1998) Top Organomet Chem 1:183;
5. (e) Lehman SE Jr, Wagener KB (2003) Catalysis in acyclic diene metathesis (ADMET) polymerization. In: Rieger B, Baugh LS, Kacker S, Striegler S (eds) Late transition metal polymerization catalysis. Wiley-VCH, Weinheim, p 193
6. (a) Yasuda H, Nakamura A (1987) Angew Chem Int Ed Engl 26:723;
7. (b) Erker G, Krüger C, Müller G (1985) Adv Organomet Chem 24:1
8. Sinn H, Kaminsky W (1980) Adv Organomet Chem 18:99
9. Ishihara N, Seimiya T, Kuramoto M, Uoi M (1986) Macromolecules 19:2464
10. Ishihara N, Kuramoto M, Uoi M (1988) Macromolecules 21:3356
11. Oliva L, Longo P, Grassi A, Ammendola P, Pellecchia C (1990) Makromol Chem Rapid Commun 11:519
12. Ricci G, Italia S, Giarrusso A, Porri L (1993) J Organomet Chem 451:67
13. Ricci G, Italia S, Porri L (1994) Macromolecules 27:868
14. Longo P, Proto A, Oliva P, Zambelli A (1996) Macromolecules 29:5500
15. Ricci G, Bosisio C, Porri L (1996) Macromol Rapid Commun 17:781
16. Longo P, Guerra G, Grisi F, Pizzuti S, Zambelli A (1998) Macromol Chem Phys 199:149
17. Pragliola S, Cipriano M, Boccia AC, Longo P (2002) Macromol Rapid Commun 23:356
18. Miyazawa A, Kase T, Soga K (1999) J Polym Sci Part A Polym Chem 37:695
19. Miyazawa A, Kase T, Soga K (2000) Macromolecules 33:2796
20. Long P, Oliva P, Proto A, Zambelli A (1996) Gazz Chim Ital 126:377
21. Pragliola S, Forlenza E, Longo P (2001) Macromol Rapid Commun 22:783
22. Ricci G, Italia S, Comitani C, Porri L (1991) Polym Commun 32:514
23. Endo K, Yamanaka Y (2001) Macromol Chem Phys 202:201
24. Ricci G, Italia S, Porri L (1994) Macromol Chem Phys 195:1389
25. Suárez PAZ, Rosa NT, Einloft S, Souza RF, Dick YP (1998) Polym Bull 41:175
26. Suárez PAZ, Silva FM, Souza RF, Dick YP (1997) Ti complex with hematein ligand also promotes cis-1,4-polymerization of butadiene. Polym Bull 39:311
27. Ricci G, Panagia A, Porri L (1996) Polymer 37:363
28. Bradley S, Camm KD, Furtado SJ, Gott AL, McGowan PC, Podesta TJ, Thornton-Pett M (2002) Organometallics 21:3443
29. Ricci G, Battistella M, Porri L (2001) Macromolecules 34:5766
30. Ricci G, Battistella M, Bertini F, Porri L (2002) Polym Bull 48:25
31. Endo K, Uchida Y (2000) J Appl Polym Sci 78:1621
32. Ricci G, Italia S, Giarrusso A, Porri L (1993) J Organomet Chem 451:67
33. (a) Costabile C, Milano G, Cavallo L, Guerra G (2001) Macromolecules 34:7952;
34. (b) Guerra G , Cavallo L, Corradini P, Fusco R (1997) Macromolecules 30:677;
35. (c) Peluso A, Improta R, Zambelli A (2000) Organometallics 19:411;
36. (d) Improta R, Peluso A (1999) Macromolecules 32:6852;
37. (e) Peluso A, Improta R, Zambelli A (1997) Macromolecules 30:2219
38. Von Dohlen WC, Wilson TP, Caflisch EG (1964) Belg Patent 644,291
39. (a) Iovu H, Hubca G, Simionescu E, Badea E, Hurst JS (1997) Eur Polym J 33:811;
40. (b) Srinivasa Rao GS, Upadhyay VK, Jain RC (1999) J Appl Polym Sci 71:595
41. Barbotin F, Spitz R, Boisson C (2001) Macromol Rapid Commun 22:1411
42. Nickaf JB, Burford RP, Chaplin RP (1995) J Polym Sci Part A Polym Chem 33:1125
43. (a) Kobayashi E, Hayashi N, Aoshima S, Furukawa J (1998) J Polym Sci Part A Polym Chem 36:1707;
44. (b) Quirk RP, Kells AM, Yunlu K, Cuif JP (2000) Polymer 41:5903
45. Friebe L, Nuyken O, Windisch H, Obrecht W (2002) Macromol Chem Phys 203:1055
46. Kwag G, Lee H, Kim S (2001) Macromolecules 34:5367
47. Evans WJ, Giarikos DG, Ziller JW (2001) Organometallics 20:5751
48. Boisson C, Barbotin F, Spitz R (1999) Macromol Chem Phys 200:1163
49. Quirk RP, Kells AM (2000) Polym Int 49:751
50. Dong W, Endo K, Masuda T (2003) Macromol Chem Phys 204:104
51. Dong W, Masuda T (2002) J Polym Sci Part A Polym Chem 40:1838
52. Natta G, Porri S, Corradini P, Zanini G, Ciampelli F (1963) J Polym Sci 51:463
53. (a) Natta G, Porri L, Stoppa G, Allegra G, Ciampelli F (1964) J Polym Sci B 1:67;
54. (b) Natta G, Porri L, Carbonaro A, Stoppa G (1964) Makromol Chem 77:114
55. (a) Porri L, Carbonaro A (1963) Makromol Chem 60:236;
56. (b) Natta G, Porri A, Carbonaro A, Ciampelli F, Allegra G (1962) Makromol Chem 51:229
57. Purevsuren B, Allegra G, Meille SV, Farina A, Porri L, Ricci G (1998) Polymer J 130:431
58. (a) Taube R, Maiwald S, Sieler J (1996) J Organomet Chem 513:37;
59. (b) Taube R, Windisch H, Maiwald S, Hemling H, Schumann H (1996) J Organomet Chem 513:49;
60. (c) Maiwald S, Weissenborn H, Sommer C, Müller G, Taube R (2001) J Organomet Chem 640:1
61. Maiwald S, Sommer C, Müller G, Taube R (2002) Macromol Chem Phys 203:1029
62. (a) Taube R, Windisch H, Weissenborn H, Hemling H, Schumann H (1997) J Organomet Chem 548:229;
63. (b) Maiwald S, Taube R, Hemling H, Schumann H (1998) J Organomet Chem 552:195
64. Maiwald S, Sommer C, Müller G, Taube R (2001) Macromol Chem Phys 202:1446
65. For reviews on polymerization by organolanthanide complexes: (a) Hou Z, Wakatsuki Y (2002) Coord Chem Rev 231:1;
66. (b) Hou Z, Wakatsuki Y (2002) J Organomet Chem 647:61
67. Cui L, Ba X, Teng H, Ying L, Li K, Jin Y (1998) Polym Bull 40:729
68. Kaita S, Hou Z, Wakatsuki Y (1999) Macromolecules 32:9078
69. Kaita S, Hou Z, Wakatsuki Y (2001) Macromolecules 34:1539
70. Kaita S, Hou Z, Nishiura M, Doi Y, Kurazumi J, Horiuchi AC, Wakatsuki Y (2003) Macromol Rapid Commun 24:179
71. Baudry-Barbier D, Andre N, Dormond A, Pardes C, Richard P, Visseaux M, Zhu CJ (1998) Eur J Inorg Chem 1721
72. Tardif O, Hou Z, Nishiura M, Koizumi T, Wakatsuki Y (2001) Organometallics 20:4565
73. Bönnemann H, Grade C, Kopp W, Wilke G (1971) Pure Appl Chem 23:265
74. Rinehart RE, Smith HP, Witt HS, Romeyn H Jr (1961) J Am Chem Soc 83:4864
75. Lobach MI, Lormer VA, Tsereteli IY, Kondoratenkov GP, Babitsikii BD, Klepikova VI (1971) J Polym Sci Polym Lett 9:71
76. Sato H, Yagi Y (1992) Bull Chem Soc Jpn 65:1299
77. Endo K, Uchida Y, Matsuda Y (1996) Macromol Chem Phys 197:3515
78. (a) Endo K, Yamanaka Y (1999) Macromol Rapid Commun 20:312;
79. (b) Endo K, Matsuda Y (1999) J Polym Sci Part A Polym Chem 37:3838;
80. Natori I, Imaizumi K, Yamagishi H, Kazunori M (1998) J Polym Sci Part B Polym Phys 36:1657
81. Nakano M, Yao Q, Usuki A, Tanimura S, Matsuoka T (2000) Chem Commun 2207
82. Tanimura S, Matsuoka T, Nakano M, Usuki A (2001) J Polym Sci Part B Polym Phys 39:973
83. Hadjiandreou P, Julémont M, Teyssié P (1984) Macromolecules 17:2455
84. Winter H, Aagaard O (1998) Macromol Rapid Commun 19:345
85. Taube R, Wache S, Kehlen H (1995) J Mol Catal A Chemical 97:21
86. Taube R, Schmidt U, Gehrke JP, Böhme P, Langlotz J, Wache S (1993) Makromol Chem Macromol Symp 66:245
87. Taube R, Windisch H, Maiwald S (1995) Macromol Symp 89:393
88. (a) Tobisch S (2002) Acc Chem Res 35:96;
89. (b) Tobisch S, Bögel H, Taube R (1996) Organometallics 15:3563;
90. (c) Tobisch S, Bögel H, Taube R (1998) Organometallics 17:1177;
91. (d) Tobisch S, Taube R (1999) Organometallics 18:5204;
92. (e) Tobisch S, Taube R (1999) Organometallics 18:3045;
93. (f) Tobisch S, Taube R (2001) Chem Eur J 7:3681;
94. (g) Tobisch S, Taube R (2002) Chem Eur J 8:4756
95. Nath DCD, Shiono T, Ikeda T (2002) Macromol Chem Phys 203:756
96. Nath DCD, Shiono T, Ikeda T (2002) Macromol Chem Phys 203:1171
97. Endo K, Hatakeyama N (2001) J Polym Sci Part A Polym Chem 39:2793
98. Endo K, Matsuda Y (2000) Macromol Chem Phys 201:1426
99. Jang Y, Kim P, Lee H (2002) Macromolecules 35:1477
100. Cass P, Pratt K, Mann T, Laslett B, Rizzardo E, Burford R (1999) J Polym Sci Part A Polym Chem 37:3277
101. Cass P, Pratt K, Mann T, Laslett B, Rizzardo E (2001) J Polym Sci Part A Polym Chem 39:2244
102. Cass P, Pratt K, Fairhall K, Laslett B, Rizzardo E (2001) J Polym Sci Part A Polym Chem 39:2256
103. Yamamoto A, Morifuji K, Ikeda S, Sato T, Uchida Y, Misono A (1968) J Am Chem Soc 90:1878
104. (a) Yamamoto T, Yamamoto A, Ikeda S (1972) Bull Chem Soc Jpn 45:1111;
105. (b) Yamamoto T, Yamamoto A, Ikeda S (1972) Bull Chem Soc Jpn 45:1140
106. (c) Yamamoto A, Shimizu T, Ikeda S (1970) Makromol Chem 136:297;
107. (d) Yamamoto T, Yamamoto A (1978) J Polym Sci Macromol Rev 13:161
108. Bazzini C, Giarrusso A, Porri L (2002) Macromol Rapid Commun 23:922
109. (a) Pellecchia C, Proto A, Zambelli A (1992) Macromolecules 25:4450;
110. (b) Zambelli A, Proto A, Longo P, Oliva P (1994) Macromol Chem Phys 195:2623;
111. (c) Longo P, Proto A, Oliva P, Sessa I, Zambelli A (1997) J Polym Sci Part A Polym Chem 35:2697
112. Pragliola S, Milano G, Guerra G, Longo P (2002) J Am Chem Soc 124:3502
113. Laird JL, Edmondson MS, Riedel JA (1997) Rubber World 217:42
114. Simanke AG, Mauler RS, Galland GB (2002) J Polym Sci Part A Polym Chem 40:471
115. (a) Barbotin F, Monteil V, Llauro MF, Boisson C, Spitz R (2000) Macromolecules 33:8521;
116. (b) Llauro MF, Monnet C, Barbotin F, Monteil V, Spitz R, Boisson C (2001) Macromolecules 34:6304
117. Visseaux M, Barbier-Baudry D, Bonnet F, Dormond A (2001) Macromol Chem Phys 202:2485
118. Bonnet F, Visseaux M, Barbier-Baudry D, Dormond A (2002) Macromolecules 35:1143
119. Bonnet F, Barbier-Baudry D, Dormond A, Visseaux M (2002) Polym Int 51:986
120. Barbier-Baudry D, Bonnet F, Domenichini B, Dormond A, Visseaux M (2002) J Organomet Chem 647:167
121. Deming TJ, Novak BM (1993) Macromolecules 26:7089
122. Deming TJ, Novak BM (1991) Macromolecules 24:5478
123. Deming TJ, Novak BM, Ziller JW (1994) J Am Chem Soc 116:2366
124. Nath DCD, Shiono T, Ikeda T (2002) J Polym Sci Part A Polym Chem 40:3086
125. Doi Y, Tokuhiro N, Soga K (1989) Makromol Chem 190:643
126. (a) Resconi L, Waymouth RM (1990) J Am Chem Soc 112:4953;
127. (b) Mogstad AL, Waymouth RM (1992) Macromolecules 25:2282;
128. (c) Cavallo L, Guerra G , Corradini P, Resconi L, Waymouth RM (1993) Macromolecules 26:260;
129. (d) Kesti MR, Waymouth RM (1992) J Am Chem Soc 114:3565
130. Schaverien CJ (1994) Organometallics 13:69
131. For reviews on enantioselective cyclopolymerization of nonconjugated dienes: Coates GW (2000) Chem Rev 100:1223
132. (a) Coates GW, Waymouth RM (1991) J Am Chem Soc 113:6270;
133. (b) Coates GW, Waymouth RM (1992) J Mol Catal 76:189;
134. (c) Coates GW, Waymouth RM (1993) J Am Chem Soc 115:91
135. Mitani M, Oouchi K, Hayakawa M, Yamada T, Mukaiyama T (1995) Chem Lett 905
136. Jayaratne KC, Sita LR (2000) J Am Chem Soc 122:958
137. Jayaratne KC, Keaton RJ, Henningsen DA, Sita LR (2000) J Am Chem Soc 122:10490
138. Lee DH, Yoon KB, Park JR, Lee BH (1997) Eur Polym J 33:447
139. Hackmann M, Repo T, Jany G, Rieger B (1998) Macromol Chem Phys 199:1511
140. Pietikäinen P, Väänänen T, Seppälä JV (1999) Eur Polym 135:1047; and references therein
141. Jeremic D, Wang Q, Quyoum R, Baird MC (1995) J Organomet Chem 497:143
142. Naga N, Shiono T, Ikeda T (1999) Macromol Chem Phys 200:1466
143. Naga N, Shiono T, Ikeda T (1999) Macromolecules 32:1348
144. Pietikäinen P, Seppälä JV, Ahjopalo L, Pietilä LO (2000) Eur Polymer J 36:183
145. Kim I, Shin YS, Lee JK (2000) J Polym Sci Part A Polym Chem 38:1590
146. Kokko E, Pietikäinen P, Koivunen J, Seppälä JV (2001) J Polym Sci Part A Polym Chem 39:3805
147. (a) Naga N, Imanishi Y (2002) Macromol Chem Phys 203:771;
148. (b) Naga N, Imanishi Y (2002) Macromol Chem Phys 203:2155
149. Jin HS, Choi CH, Park ES, Lee IM, Yoon JS (2002) J Appl Polym Sci 84:1048
150. Santos JM, Ribeiro MR, Portela MF, Cramail H, Deffieux A (2001) Macromol Chem Phys 202:3043
151. Arnold M, Bornemann S, Schimmel T, Heinze T (2002) Macromol Symp 181:5
152. Hustad PD, Tian J, Coates GW (2002) J Am Chem Soc 124:3614
153. Hustad PD, Coates GW (2002) J Am Chem Soc 124:11578
154. (a) Mori H, Kono H, Terano M (2000) Macromol Chem Phys 201:543;
155. (b) Kono H, Mori H, Terano M (2001) Macromol Chem Phys 202:1319;
156. (c) Kono H, Ichiki T, Mori H, Nakatani H, Terano M (2001) Polym Int 50:568
157. (a) Greenfield H, Wender I, Wotiz JH (1956) J Org Chem 21:875;
158. (b) Baker Jr WP (1963) J Polym Sci Part A 1:655;
159. (c) Otsuka S, Mori K, Imaizumi F (1965) J Am Chem Soc 87:3017;
160. (d) Otsuka S, Nakamura A (1967) J Polym Sci Polym Lett 5:973;
161. (e) Otsuka S, Mori K, Suminoe T, Imaizumi F (1967) Eur Polym J 3:73;
162. (f) Krentsel BA, Mushina EA, Khar'kova EM, Shishkina MV (1975) Eur Polym J 11:865;
163. (g) Leland J, Boucher J, Anderson K (1977) J Polym Sci Part A Polym Chem 15:2785;
164. (h) Ghalamkar-Moazzam M, Jacobs TL (1978) J Polym Sci Part A Polym Chem 16:615
165. (a) Scholten JP; van der Ploeg HJ (1972) J Polym Sci Polym Chem Ed 10:3067;
166. (b) Scholten JP, van der Ploeg HJ (1973) J Polym Sci Polym Chem Ed 11:3205
167. (a) Endo T, Tomita I (1997) Prog Polym Sci 46:79;
168. (b) Tomita I, Takagi K, Endo T (1998) J Synth Org Chem Jpn 56:260
169. Takagi K, Tomita I, Endo T (1997) Macromolecules 30:7386
170. Endo T, Takagi K, Tomita I (1997) Tetrahedron 53:15187
171. Takagi K, Tomita I, Endo T (1997) Chem Lett 1187
172. Tomita I, Kondo Y, Takagi K, Endo T (1994) Macromolecules 27:4413
173. Tomita I, Kondo Y, Takagi K, Endo T (1995) Acta Polym 46:432
174. Takagi K, Tomita I, Nakamura Y, Endo T (1998) Macromolecules 31:2779
175. Tomita I, Abe T, Takagi K, Endo T (1995) J Polym Sci Part A Polym Chem 33:2487
176. Taguchi M, Tomita I, Yoshida Y, Endo T (2000) Macromol Chem Phys 201:1025
177. Takagi K, Tomita I, Endo T (1997) Polym Bull 39:685
178. Takagi K, Tomita I, Endo T (1998) Chem Commun 681
179. Tomita I, Ubukata M, Endo T (1998) React Funct Polym 37:27
180. Takagi K, Tomita I, Endo T (1998) Macromolecules 31:6741
181. Suzuki M, Takao T, Sakamoto N, Tomita I, Endo T (1999) Polym J 31:1021
182. Taguchi M, Tomita I, Endo T (2000) Macromol Chem Phys 201:2322
183. Wang J, Tomita I, Endo T (2001) Macromolecules 34:4294
184. Taguchi M, Tomita I, Endo T (2000) Angew Chem Int Ed 39:3667
185. Nakano M, Novak BM (1996) ACS Polym Prepr 37:200
186. Novak BM, Nakano M (1997) Polym Mater Sci Eng 76:102
187. (a) Deming TJ, Novak BM (1991) Macromolecules 24:6043;
188. (b) Deming TJ, Novak BM (1993) J Am Chem Soc 115:9101
189. Tomita I, Taguchi M, Takagi K, Endo T (1997) J Polym Sci Part A Polym Chem 35:431
190. Taguchi M, Tomita I, Yoshida Y, Endo T (1999) J Polym Sci Part A Polym Chem 37:3916
191. Taguchi M, Tomita I, Yoshida Y, Endo T (2001) J Polym Sci Part A Polym Chem 39:495
192. (a) Nakamura A (1966) Bull Chem Soc Jpn 39:543;
193. (b) Bowden FL, Giles R (1976) Coord Chem Rev 20:81
194. Sovago J, Newton MG, Mushina EA, Ungváry F (1996) J Am Chem Soc 118:9589
195. Szalontai G, Sóvágó J, Ungváry F (1999) J Organomet Chem 586:54
196. Choi JC, Osakada K, Yamaguchi I, Yamamoto T (1997) Appl Organomet Chem 11:957
197. For reviews of transition metal-catalyzed reactions of methylenecyclopropanes: (a) Binger P, Büch HM (1987) Top Curr Chem 135:77;
198. (b) Nakamura I, Yamamoto Y (2002) Adv Synth Cat 344:111
199. Harrington PJ (1995) Transition metal allyl complexes: trimethylene methane complexes. In: Abel EW, Stone FGA, Wilkinson G (eds) Comprehensive organometallic chemistry, vol 12, Chap 8.4. Pergamon, Oxford, p 923
200. (a) Osakada K, Takimoto H, Yamamoto T (1999) J Chem Soc Dalton Trans 853;
201. (b) Nishihara Y, Yoda C, Osakada K (2001) Organometallics 20:2124
202. (a) Nishihara Y, Itazaki M, Osakada K (2002) J Org Chem 67:6889;
203. (b) Nishihara Y, Itazaki M, Osakada K (2002) Tetrahedron Lett 43:2059
204. (a) Pinazzi CP, Brossas J (1969) Makromol Chem 122:105;
205. (b) Pinazzi CP, Brossas J (1971) Makromol Chem 147:15;
206. (c) Pinazzi CP, Brossas J, Clouet G (1971) Makromol Chem 148:81
207. Rossi R, Diversi P, Porri L (1972) Macromolecules 5:247
208. Yang X, Jia L, Marks TJ (1993) J Am Chem Soc 115:3392
209. Jia L, Yang X, Seyam AM, Albert IDL, Fu PF, Yang S, Marks TJ (1996) J Am Chem Soc 118:7900
210. Jia L, Yang X, Yang S, Marks TJ (1996) J Am Chem Soc 118:1547
211. Yang X, Seyam AM, Fu PF, Marks TJ (1994) Macromolecules 27:4625
212. Takeuchi D, Kim S, Osakada K (2001) Angew Chem Int Ed 40:2685
213. Kim S, Takeuchi D, Osakada K (2003) Pd complex-catalyzed ring-opening polymerisation of 2-aryl-1-methylenecyclopropanes. In: Screttas CG, Steele BR (eds) Perspectives in organometallic chemistry. The Royal Society of Chemistry, Cambridge, p 306
214. Aeby A, Gsponer A, Consiglio G (1998) J Am Chem Soc 120:11000
215. Hughes RP, Powell J (1972) J Am Chem Soc 94:7723
216. (a) Burger BJ, Thompson ME, Cotter WD, Bercaw JB (1990) J Am Chem Soc 112:1566;
217. (b) Takaya M, Kageyama A, Miya S, Yamazaki H (1991) Chem Lett 20:1525;
218. (c) Resconi L, Piemontesi F, Franciscono G, Abis L, Fiorani T (1992) J Am Chem Soc 114:1025;
219. (d) Eshuis JJW, Tan YY, Meetsma A, Teuben JH, Renkema J, Evens GG (1992) Organometallics 11:362;
220. (e) Guo Z, Swenson DC, Jordan RF (1994) Organometallics 13:1424
221. Takeuchi D, Osakada K (2002) Chem Commun 646
222. Takeuchi D, Anada K, Osakada K (2002) Macromolecules 35:9628
223. Chatani N, Takeyasu T, Hanafusa T (1988) Tetrahedron Lett 29:3979
224. For reviews of copolymerization of alkene and CO: (a) Drent E, Budzelaar PHM (1996) Chem Rev 96:663;
225. (b) Sen A (1993) Acc Chem Res 26:303;
226. (c) Sperrle M, Consiglio G (1997) Chem Ber 130:1557;
227. (d) Nozaki K, Hiyama T (1999) J Organomet Chem 576:248
228. (a) Brookhart M, Rix FC, DeSimone JM, Barborak JC (1992) J Am Chem Soc 114:5894;
229. (b) Brookhart M, Wagner MI, Balavoine GGA, Haddou HA (1994) J Am Chem Soc 116:3641;
230. (e) Bronco S, Consiglio G, Hutter R, Batistini A, Suter UW (1994) Macromolecules 27:4436;
231. (d) Sesto B, Consiglio G (2001) J Am Chem Soc 123:4097;
232. (e) Nozaki K, Sato N, Takaya H (1995) J Am Chem Soc 117:9911;
233. (f) Nozaki K, Komaki H, Kawashima Y, Hiyama T, Matsubara T (2001) J Am Chem Soc 123:534
234. Borkowsky SL, Waymouth RM (1996) Macromolecules 29:6377
235. Nozaki K, Sato N, Nakamoto K, Takaya H (1997) Bull Chem Soc Jpn 70:659
236. Kettunen M, Abu-Surrah AS, Repo T, Leskelä M (2001) Polym Int 50:1223
237. Maatschappij BV (1988) Neth Appl 8801168 (1990) Chem Abstr 113:24686f
238. Kacker S, Sen A (1997) J Am Chem Soc 119:10028
239. (a) Wang L, Flood TC (1992) J Am Chem Soc 114:3169;
240. (b) Wang L, Lu RS, Bau R, Flood TC (1993) J Am Chem Soc 115:6999
241. (a) Zhang SW, Takahashi S (2000) Chem Commun 315;
242. (b) Zhang SW, Kaneko T, Takahashi S (2000) Macromolecules 33:6930
243. Choi JC, Osakada K, Yamamoto T (1998) Organometallics 17:3044
244. Osakada K, Choi JC, Yamamoto T (1997) J Am Chem Soc 119:12390
245. Choi JC, Yamaguchi I, Osakada K, Yamamoto T (1998) Macromolecules 31:8731
246. Osakada K, Takenaka Y, Choi JC, Yamaguchi I, Yamamoto T (2000) J Polym Sci Part A Polym Chem 38:1505
247. Takenaka Y, Osakada K (2001) Macromol Chem Phys 202:3571
248. Takenaka Y, Osakada K, Nakano M, Ikeda T (2003) Macromolecules 36:1414
249. Kim S, Takeuchi D, Osakada K (2002) J Am Chem Soc 124:762
250. Kim S, Takeuchi D, Osakada K (2003) Macromol Chem Phys 204:666
251. Takeuchi D, Yasuda A, Osakada K (2003) J Chem Soc Dalton Trans 2029
252. Syndiotactic and isotactic denote the stereochemistry of the polymer of the substituted alkenes such as propylene and methyl methacrylate. In Scheme 20, the stereo-chemical relationships of the neighboring cyclohexane groups along the polymer chain are expressed using this terminology, although the original definition of syndiotactic and isotactic does not cover such polymers. The stereochemistry of several polymers in this review is expressed according to each of the original papers