Synthesis and diphosphine ligand fluxionality in Os3(CO)10(bmi): Kinetic evidence for nondissociative diphosphine isomerization and X-ray crystal structure of 1,1-Os3(CO)10(bmi)

Journal of Organometallic Chemistry

Volumn 691, Issue 22, 2006, Pages 4676-4685

  Watson, William H ^a   Poola, Bhaskar ^b   Richmond, Michael G ^b  

^a TEXAS CHRISTIAN UNIVERSITY   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

Diphosphine ligand fluxionality; Kinetics; Ortho metalation; Osmium clusters

Indexed keywords

DIPHOSPHINE LIGAND FLUXIONALITY; ORTHO METALATION; OSMIUM CLUSTERS;

CHELATION; CRYSTAL STRUCTURE; ISOMERIZATION; OSMIUM COMPOUNDS; REACTION KINETICS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

ORGANOMETALLICS;

EID: 33749556716     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.07.040     Document Type: Article

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