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Volumn 691, Issue 17, 2006, Pages 3609-3616

Ligand substitution in HC(O)CCo3(CO)9 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine ligand fluxionality, decarbonylation of the formyl moiety and competitive P-Ph bond cleavage reactivity

Author keywords

Decarbonylation; Ligand substitution; P Ph bond cleavage; Tetrahedral clusters

Indexed keywords

DECARBONIZATION; ELECTRONS; INFRARED RADIATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLICS; THERMOANALYSIS; TOLUENE; X RAY DIFFRACTION;

EID: 33745920169     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.05.029     Document Type: Article
Times cited : (18)

References (55)
  • 4
    • 33745905365 scopus 로고    scopus 로고
    • Unpublished results (R = Me and Cl).
  • 5
    • 33644610621 scopus 로고    scopus 로고
    • For reports of phosphine ligand isomerization about a cluster polyhedron, see:
    • For reports of phosphine ligand isomerization about a cluster polyhedron, see:. Watson W.H., Wu G., and Richmond M.G. Organometallics 25 (2006) 930
    • (2006) Organometallics , vol.25 , pp. 930
    • Watson, W.H.1    Wu, G.2    Richmond, M.G.3
  • 21
    • 33745911370 scopus 로고    scopus 로고
    • saint Version 6.02, Bruker Analytical X-ray Systems Inc., Copyright 1997-1999.
  • 22
    • 33745908648 scopus 로고    scopus 로고
    • shelxtl Version 5.1, Bruker Analytical X-ray Systems Inc., Copyright 1998.
  • 28
    • 13144295040 scopus 로고    scopus 로고
    • For examples of this phenomenon in related mixed-metal clusters, see:
    • For examples of this phenomenon in related mixed-metal clusters, see:. Bott S.G., Yang K., Huang S.-H., and Richmond M.G. J. Chem. Crystallogr. 34 (2004) 883
    • (2004) J. Chem. Crystallogr. , vol.34 , pp. 883
    • Bott, S.G.1    Yang, K.2    Huang, S.-H.3    Richmond, M.G.4
  • 43
    • 37049142343 scopus 로고
    • The adoption of bridging carbonyl groups upon ligand substitution in this family of tricobalt clusters is a well-documented phenomenon:
    • The adoption of bridging carbonyl groups upon ligand substitution in this family of tricobalt clusters is a well-documented phenomenon:. Matheson T.W., Robinson B.H., and Tham W.S. J. Chem. Soc., Dalton Trans. (1971) 1457
    • (1971) J. Chem. Soc., Dalton Trans. , pp. 1457
    • Matheson, T.W.1    Robinson, B.H.2    Tham, W.S.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.