Ligand substitution in the mixed-metal cluster PhCCo2Ni(CO) 6Cp by 2,3-bis(diphenylphosphino)maleic anhydride (bma): An intimate picture involving the stepwise conversion of the trinuclear cluster PhCCo 2Ni(CO)4(η2-bma)Cp to the mononuclear compound CpNi[PPh2CPhCC(PPh2)C(O)OC(O)]

Journal of Organometallic Chemistry

Volumn 690, Issue 12, 2005, Pages 3067-3079

  Bott, Simon G ^a   Yang, Kaiyuan ^b   Richmond, Michael G ^b  

^a University of Houston   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

Diphosphine fluxional behavior; Mixed metal clusters; P C bond cleavage; VT IR

Indexed keywords

CARBON MONOXIDE; CHEMICAL BONDS; COMPLEXATION; COORDINATION REACTIONS; SOLUTIONS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

DIPHOSPHINE FLUXIONAL BEHAVIOR; MIXED-METAL CLUSTERS; P-C BOND CLEAVAGE; VT IR;

SUBSTITUTION REACTIONS;

EID: 19744383986     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.01.069     Document Type: Article

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