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3): δ 75.95 (s).
-
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30
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0000537782
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For examples of bridged alkenyl clusters resulting from alkyne insertion into a metal-hydride bond and facile alkenyl decoordination/recoordination reactivity, see: (a) Lugan, N.; Laurent, F.; Lavigne, G.; Newcomb, T. P.; Liimatta, E. W.; Bonnet, J.-J. J. Am. Chem. Soc. 1990, 112, 8607.
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0037575362
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note
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2] in ca. a 45:55 ratio, which suggests that the chromatographic support used in the isolation of these clusters does not promote hydride scrambling over the alkenyl moiety.
-
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35
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0038250965
-
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note
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Additional experiments are planned in order to investigate and resolve the sequence concerning the phenyl and hydride transfer in these acetylide clusters.
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36
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0040065993
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