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Volumn 22, Issue 9, 2003, Pages 1953-1959

Acetylide participation in ligand substitution and P-C bond cleavage in the reaction between HRu3(CO)9 (see abstract)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CRYSTAL STRUCTURE; HIGH TEMPERATURE EFFECTS; HYDRIDES; HYDROGEN; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM COMPOUNDS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

EID: 0038340079     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0300169     Document Type: Article
Times cited : (45)

References (50)
  • 14
    • 0037575367 scopus 로고
    • For examples of nucleophilic attack on a coordinated acetylide ligand in di- and trimetal complexes, see: (a) Jensen, M. P.; Shriver, D. F. Organometallics 1992, 11, 3385.
    • (1992) Organometallics , vol.11 , pp. 3385
    • Jensen, M.P.1    Shriver, D.F.2
  • 18
    • 1542477285 scopus 로고
    • For chelating diphosphines that exhibit a large nuclear deshielding upon coordination, see: (a) Garrou, P. E. Chem. Rev. 1981, 81, 229.
    • (1981) Chem. Rev. , vol.81 , pp. 229
    • Garrou, P.E.1
  • 29
    • 0038589470 scopus 로고    scopus 로고
    • note
    • 3): δ 75.95 (s).
  • 34
    • 0037575362 scopus 로고    scopus 로고
    • note
    • 2] in ca. a 45:55 ratio, which suggests that the chromatographic support used in the isolation of these clusters does not promote hydride scrambling over the alkenyl moiety.
  • 35
    • 0038250965 scopus 로고    scopus 로고
    • note
    • Additional experiments are planned in order to investigate and resolve the sequence concerning the phenyl and hydride transfer in these acetylide clusters.
  • 40
    • 0040065993 scopus 로고
    • For related examples involving the formation of a phosphonium moiety via diphosphine ligand attack on a coordinated alkyne, see: (a) Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1994, 13, 3767.
    • (1994) Organometallics , vol.13 , pp. 3767
    • Yang, K.1    Bott, S.G.2    Richmond, M.G.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.