Phosphine ligand attack at both the methylidyne cap and the CpNi center in HCCo2NiCp(CO)6 by 2,3-bis(diphenylphosphino)maleic anhydride (bma)

Organometallics

Volumn 22, Issue 7, 2003, Pages 1383-1390

  Bott, Simon G ^a   Yang, Kaiyuan ^b   Talafuse, Kathleen A ^b   Richmond, Michael G ^b  

^a University of Houston   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; HYDROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; REDOX REACTIONS; STRUCTURE (COMPOSITION); SUBSTITUTION REACTIONS; THERMOANALYSIS; ULTRAVIOLET SPECTROSCOPY;

SOLID-STATE STRUCTURES;

ORGANOMETALLICS;

EID: 0037474874     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0209273     Document Type: Article

References (93)

1. (a) Fenske, D.; Becher, H. J. Chem. Ber. 1974, 107, 117; 1975, 108, 2115.
2. (a) Fenske, D.; Becher, H. J. Chem. Ber. 1974, 107, 117; 1975, 108, 2115.
3. (b) Fenske, D. Angew. Chem., Int. Ed. Engl. 1976, 15, 381.
4. (c) Fenske, D. Chem. Ber. 1979, 112, 363.
5. (d) Bensmann, W.; Fenske, D. Angew. Chem., Int. Ed. Engl. 1979, 18, 677.
6. (e) Fenske, D.; Christidis, A. Angew. Chem., Int. Ed. Engl. 1981, 20, 129.
7. (a) Mao, F.; Tyler, D. R.; Keszler, D. J. Am. Chem. Soc. 1989, 111, 130.
8. (b) Fei, M.; Sur, S. K.; Tyler, D. R. Organometallics 1991, 10, 419.
9. (c) Mao, F.; Tyler, D. R.; Bruce, M. R. M.; Bruce, A. E.; Rieger, A. L.; Rieger, P. H. J. Am. Chem. Soc. 1992, 114, 6418.
10. (d) Meyer, R.; Schut, D. M.; Keana, K. J.; Tyler, D. R. Inorg. Chim. Acta 1995, 240, 405.
11. (e) Schut, D. M.; Keana, K. J.; Tyler, D. R.; Rieger, P. H. J. Am. Chem. Soc. 1995, 117, 8939.
12. Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1995, 14, 2387.
13. Lewis, J. S.; Health, S. L.; Powell, A. K.; Zweit, J.; Blower, P. J. J. Chem. Soc., Dalton Trans. 1997, 855.
14. Duffy, N. W.; Nelson, R. R.; Richmond, M. G.; Rieger, A. L.; Rieger, P. H.; Robinson, B. H.; Tyler, D. R.; Wang, J. C.; Yang, K. Inorg. Chem. 1998, 37, 4849.
15. (a) Tyler, D. R.; Mao, F. Coord. Chem. Rev. 1990, 97, 119.
16. (b) Tyler, D. R. Acc. Chem. Res. 1991, 24, 325.
17. For an early definition of this parameter, see: Brown, T. L. In Organometallic Radical Processes; Trogler, W. C., Ed.; Elsevier: New York, 1990; Chapter 3.
18. (a) Astruc, D. Electron Transfer and Radical Processes in Transition-Metal Chemistry; Wiley-VCH: New York, 1995.
19. (b) Kochi, J. K. J. Organomet. Chem. 1986, 300, 139.
20. (c) Robinson, B. H.; Simpson, J. In Paramagnetic Organometallic Species in Activation / Selectivity, Catalysis; Chanon, M., Julliard, M., Poite, J. C., Eds.; Kluwer Academic Press: Boston, 1989; p 357.
21. Klein, A.; Volger, C.; Kaim, W. Organometallics 1996, 15, 236.
22. For bma-substituted dinuclear complexes, see: (a) Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1994, 13, 3767; 3788; 1995, 14, 4977.
23. For bma-substituted dinuclear complexes, see: (a) Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1994, 13, 3767; 3788; 1995, 14, 4977.
24. (b) Yang, K.; Bott, S. G.; Richmond, M. G. J. Organomet. Chem. 1996, 516, 65.
25. (c) Bott, S. G.; Yang, K.; Wang, J. C.; Richmond, M. G. Inorg. Chem. 2000, 39, 6051.
26. (a) Yang, K.; Smith, J. M.; Bott, S. G.; Richmond, M. G. Organometallics 1993, 12, 4779.
27. (b) Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1995, 14, 919; 2718.
28. (c) Yang, K.; Martin, J. A.; Bott, S. G.; Richmond, M. G. Organometallics 1996, 15, 2227.
29. (d) Shen, H.; Bott, S. G.; Richmond, M. G. Inorg. Chim. Acta 1996, 250, 195.
30. (e) Xia, C.-G.; Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1996, 75, 4480.
31. (a) Shen, H.; Bott, S. G.; Richmond, M. G. Organometallics 1995, 14, 4625.
32. (b) Shen, H.; Williams, T. J.; Bott, S. G.; Richmond, M. G. J. Organomet. Chem. 1995, 505, 1.
33. (c) Bott, S. G.; Wang, J. C.; Shen, H.; Richmond, M. G. J. Chem. Crystallogr. 1999, 29, 391.
34. (d) Bott, S. G.; Shen, H.; Richmond, M. G. Struct. Chem. 2001, 12, 225; 237.
35. For a report involving the P-C bond activation of the bma ligand by a mononuclear complex, see: Bensmann, W.; Fenske, D. Angew. Chem., Int. Ed. Engl. 1978, 17, 462.
36. Unpublished results.
37. 3-vinylidene ligands in trimetal clusters, see: (a) Ching, S.; Sabat, M.; Shriver, D. F. Organometallics 1989, 8, 1047.
38. (b) Ching, S.; Jensen, M. P.; Sabat, M.; Shriver, D. F. Organometallics 1989, 8, 1058.
39. (c) Albiez, T.; Heineke, D.; Vahrenkamp, H. Chem. Ber. 1991, 124, 1025.
40. (a) Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1982, 21, 711.
41. (b) Albright, T. A.; Burdett, J. K.; Whangbo, M. H. Orbital Interactions in Chemistry; Wiley: New York, 1985.
42. Schacht, H. T.; Vahrenkamp, H. J. Organomet. Chem. 1990, 381, 261.
43. (a) Koelle, U. J. Organomet. Chem. 1977, 133, 53.
44. (b) Albers, M. O.; Coville, N. J. Coord. Chem. Rev. 1984, 53, 227.
45. 18C NMR resonances, see: (a) Yuan, P.; Richmond, M. G.; Schwartz, M. Inorg. Chem. 1990, 30, 679.
46. (b) Richmond, M. G.; Kochi, J. K. Organometallics 1987, 6, 254.
47. (a) Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prentice Hall: Englewoods Cliffs, NJ, 1990.
48. (b) Mingos, D. M. P.; May, A. S. In The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; VCH Publishers: New York, 1990; Chapter 2.
49. (a) Beurich, H.; Blumhofer, R.; Vahrenkamp, H. Chem. Ber. 1982, 115, 2409.
50. (b) Blumhofer, R.; Fischer, K.; Vahrenkamp, H. Chem. Ber. 1986, 119, 194.
51. (c) Einstein, F. W. B.; Tyers, K. G.; Tracey, A. S.; Sutton, D. Inorg. Chem. 1986, 25, 1631.
52. Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1995, 14, 919.
53. For related studies that document the reversible polyhedral opening of a tetrahedrane cluster by phosphine addition, see: (a) Planalp, R. P.; Vahrenkamp, H. Organometallics 1987, 6, 492.
54. (b) Schneider, J.; Minelli, M.; Huttner, G. J. Organomet. Chem. 1985, 294, 75.
55. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc., Dalton Trans. 1989, S1.
56. (a) Albright, T. A.; Kang, S.-K.; Arif, A. M.; Bard, A. J.; Jones, R. A.; Leland, J. K.; Schwab, S. T. Inorg. Chem. 1988, 27, 1246.
57. (b) Caffyn, A. J. M.; Mays, M. J.; Solan, G. A.; Conole, G.; Tiripicchio, A. J. Chem. Soc., Dalton Trans. 1993, 2345.
58. (a) Espenson, J. H. Chemical Kinetics and Reaction Mechanisms, 2nd ed.; McGraw-Hill: New York, 1995.
59. (b) Jordan, R. B. Reaction Mechanisms of Inorganic and Organometallics; Oxford Press: New York, 1998.
60. 1[cluster 2].
61. (a) Beurich, H.; Vahrenkamp, H. Chem. Ber. 1981, 114, 2542.
62. (b) Colin, J.; Jossart, C.; Balavoine, G. Organometallics 1986, 5, 203.
63. (c) Aime, S.; Botta, M.; Gobetto, R.; Osella, D. J. Organomet. Chem. 1987, 320, 229.
64. (d) Downard, A. J.; Robinson, B. H.; Simpson, J. Organometallics 1986, 5, 1122, 1132, 1140.
65. (e) Watson, W. H.; Nagl, A.; Hwang, S.; Richmond, M. G. J. Organomet. Chem. 1993, 445, 163.
66. (f) Yang, K.; Bott, S. G.; Richmond, M. G. J. Organomet. Chem. 1993, 454, 273.
67. (g) Don, M.-J.; Richmond, M. G.; Watson, W. H.; Krawiec, M.; Kashyap, R. P. J. Organomet. Chem. 1991, 418, 231.
68. (a) Klopman, G. J. Am. Chem. Soc. 1968, 90, 223.
69. (b) Klopman, G. In Chemical Reactivity and Reaction Paths; Klopman, G., Ed.; Wiley: New York, 1974; Chapter 4.
70. DeKock, R. L.; Deshmukh, P.; Dutta, T. K.; Fehlner, T. P.; Housecraft, C. E.; Hwang, J. L.-S. Organometallics 1983, 2, 1108.
71. (a) Strouse, C. E.; Dahl, L. F. J. Am. Chem. Soc. 1971, 93, 6032.
72. (b) Schilling, B. E. R.; Hoffmann, R. J. Am. Chem. Soc. 1979, 101, 3456.
73. (c) Matheson, T. W.; Peake, B. M.; Robinson, B. H.; Simpson, J.; Watson, D. J. J. Chem. Soc., Chem. Commun. 1973, 894.
74. (d) Peake, B. M.; Robinson, B. H.; Simpson, J.; Watson, D. J. Inorg. Chem. 1977, 16, 405.
75. (e) Peake, B. M.; Rieger, P. H.; Robinson, B. H.; Simpson, J. Inorg. Chem. 1979, 18, 1000; 1981, 20, 2540.
76. (e) Peake, B. M.; Rieger, P. H.; Robinson, B. H.; Simpson, J. Inorg. Chem. 1979, 18, 1000; 1981, 20, 2540.
77. (h) Beurich, H.; Madach, T.; Richter, F.; Vahrenkamp, H. Angew. Chem., Int. Ed. Engl. 1979, 18, 690.
78. (a) Unpublished results.
79. 31P chemical shifts at δ 23.5 and 28.4 (73%) and δ 21.8 and 27.2 (27%).
80. For reports on the ability of cluster-bound phosphines to bridge contiguous metal centers and participate in intramolecular migrations, see: (a) Bradford, A. M.; Douglas, G.; Manojlovic-Muir, L.; Muir, K. W.; Puddephatt, R. J. Organometallics 1990, 9, 409.
81. (b) Bouherour, S.; Braunstein, P.; Róse, J.; Toupet, L. Organometallics 1999, 18, 4908.
82. (c) Adams, R. D.; Captain, B.; Fu, W.; Pellechia, P. J. Chem. Commun. 2000, 937.
83. (d) See also refs 10a,b and 11a,d.
84. 31 P NMR measurements (1D and 2D techniques).
85. (a) Seyferth, D.; Nestle, M. O.; Hallgren, J. S. Inorg. Synth. 1980, 20, 224.
86. (b) Seyferth, D.; Hallgren, J. S.; Hung, P. L. K. J. Organomet. Chem. 1973, 50, 265.
87. Mao, F.; Philbin, C. E.; Weakley, T. J. R.; Tyler, D. R. Organometallics 1990, 9, 1510.
88. King, R. B. Organometallic Syntheses; Academic Press: New York, 1965; Vol. 1.
89. Shriver, D. F. The Manipulation of Air-Sensitive Compounds; McGraw-Hill: New York, 1969.
90. Carpenter, B. K. Determination of Organic Reaction Mechanisms; Wiley-Interscience: New York, 1984.
91. (a) Hoffmann, E.; Lipscomb, W. N. J. Chem. Phys. 1962, 36, 2179, 3489.
92. (b) Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
93. Mealli, C.; Proserpio, D. M. J. Chem. Educ. 1990, 67, 399.