Thermally induced dual P-C bond cleavage routes from the imido-capped cluster (see abstract)

Journal of Organometallic Chemistry

Volumn 689, Issue 21, 2004, Pages 3426-3437

  Bott, Simon G ^a,b   Shen, Huafeng ^a,b   Richmond, Michael G ^a,b  

^a University of Houston   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

Diphosphine ligand; Electrochemistry; Imido capped clusters; Metal clusters; P C bond activation; Redox chemistry

Indexed keywords

CARBON; PHOSPHATE; PHOSPHINE DERIVATIVE; PHOSPHORUS 31; RUTHENIUM DERIVATIVE;

ARTICLE; CHELATION; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTROCHEMISTRY; LIGAND BINDING; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY; SYNTHESIS; THERMAL ANALYSIS; X RAY DIFFRACTION;

EID: 4644257538     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.07.056     Document Type: Article

References (77)

1. (a) G. Süss-Fink G. Meister Adv. Organomet. Chem. 35 1993 41
2. (b) G. Lavigne B. de Bonneval R.D. Adams F.A. Cotton Catalysis by Di- and Polynuclear Metal Cluster Compounds 1998 Wiley-VCH New York (Chapter 2)
3. (a) S. Cenini M. Pizzotti C. Crotti F. Porta G. La Monica Chem. Commun. 1984 1286
4. (b) A. Basu S. Bhaduri H. Khwaja J. Organomet. Chem. 319 1987 C28
5. Han S.-H. Song J.-S. Macklin P.D. Nguyen S.T. geoffroy G.L. Rheingold A.L. Organometallics 8 1989 2127
6. (a) S. Cenini C. Crotti M. Pizzotti F. Porta J. Org. Chem. 53 1988 1243
7. (b) A. Bassoli B. Rindone S. Cenini J. Mol. Catal. 66 1991 163
8. (c) S.-H. Han G.L. Geoffroy A.L. Rheingold Inorg. Chem. 26 1987 3426
9. (a) S. Bhaduri H. Khwaja N. Sapre K. Sharma A. Basu P.G. Jones G. Carpenter J. Chem. Soc. Dalton Trans. 1990 1313
10. (b) F. Ragaini J.-S. Song D.L. Ramage G.L. Geoffroy G.A.P. Yap A.L. Rheingold Organometallics 14 1995 387
11. (a) S.-H. Han G.L. Geoffroy A.L. Rheingold Organometallics 6 1987 2380
12. (b) J.-S. Song S.-H. Han S.T. Nguyen G.L. Geoffroy A.L. Rheingold Organometallics 9 1990 2386
13. (a) M.I. Bruce P.E. Corbin P.A. Humphrey G.A. Koutsantonis M.J. Liddell E.R.T. Tiekink J. Chem. Soc. Chem. Commun. 1990 674
14. (b) Y. Chi L.-K. Liu G. Huttner L. Zsolnai J. Organomet. Chem. 390 1990 C50
15. (c) M.I. Bruce E. Horn P.A. Humphrey E.R.T. Tiekink J. Organomet. Chem. 518 1996 121
16. (d) C.-W. Pin Y. Chi C. Chung A.J. Carty S.-M. Peng G.-H. Lee Organometallics 17 1998 4146
17. (a) D. Wang H. Shen M.G. Richmond M. Schwartz Inorg. Chim. Acta 236 1995 1
18. (b) D. Wang H. Shen M.G. Richmond M. Schwartz Organometallics 14 1995 3636
19. H. Shen R.A. Senter S.G. Bott M.G. Richmond Inorg. Chim. Acta 247 1996 161
20. Pizzotti M. Porta F. Cenini S. Demartin F. Organomet J. Chem. 356 1988 105
21. (b) M. Pizzotti S. Cenini C. Crotti F. Demartin J. Organomet. Chem. 375 1989 123
22. Bott S.G. Shen H. Richmond M.G. Struct Chem. 12 2001 225
23. (b) S.G. Bott K. Yang J.C. Wang M.G. Richmond Inorg. Chem. 39 2000 6051
24. (a) For related bma-substituted compounds and ligand-cluster reactivity see: Xia C.-G. Yang K. Bott S.G. Richmond M.G. Organometallics 15 1996 4480
25. (b) S.G. Bott K. Yang K.A. Talafuse M.G. Richmond Organometallics 22 2003 1383
26. Yang K. Smith J.M. Bott S.G. Richmond M.G. Organometallics 12 1993 4779
27. (a) D. Fenske H. Becher Chem. Ber. 107 1974 117
28. (b) D. Fenske Chem. Ber. 112 1979 363
29. J.A. Smieja W.L. Gladfelter Inorg. Chem. 25 1986 2667
30. M.I. Bruce C.M. Jensen N.L. Jones Inorg. Synth. 26 1989 259
31. D.F. Shriver The Manipulation of Air-Sensitive Compounds 1969 McGraw-Hill New York
32. K. Yang S.G. Bott M.G. Richmond Organometallics 14 1995 2387
33. (a) R. Hoffmann W.N. Lipscomb J. Chem. Phys. 36 1962 2179
34. (b) R. Hoffmann J. Chem. Phys. 39 1963 1397
35. C. Mealli D.M. Proserpio J. Chem. Ed. 67 1990 399
36. R.C. Weast Handbook of Chemistry and Physics 56th ed. 1975 CRC Press Cleveland, OH
37. 3 , see: H. Shen S.G. Bott M.G. Richmond Inorg. Chim. Acta 241 1996 71
38. (b) D. Cauzzi C. Graiff C. Massera G. Predieri A. Tiripicchio D. Acquotti J. Chem. Soc. Dalton Trans. 1999 3515
39. D.M.P. Mingos D.J. Wales Introduction to Cluster Chemistry 1990 Prentice Hall Englewood Cliffs, NJ
40. S. Bhaduri K.S. Gopalkrishnan G.M. Sheldrick W. Clegg D. Stalke J. Chem. Soc. Dalton Trans. 1983 2339
41. (a) M.R. Churchill R.A. Lashewycz J.R. Shapley S.I. Richter Inorg. Chem. 19 1980 1277
42. (b) P.E. Garrou Chem. Rev. 81 1981 229
43. (c) M.G. Richmond J.K. Kochi Organometallics 6 1987 254
44. Bott S.G. Yang K. Richmond M.G. J. Organomet. Chem. 689 2004 791
45. (b) S.G. Bott H. Shen R.A. Senter M.G. Richmond Organometallics 22 2003 1953
46. (c) H. Shen S.G. Bott M.G. Richmond Organometallics 14 1995 4625
47. A.J. Carty S.A. MacLaughlin D. Nucciarone J.G. Verkade L.D. Quin Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis 1987 VCH Publishers New York
48. (a) J.A. Cabeza I. del Río S. García-Granda V. Riera M. Suárez Organometallics 21 2002 5055
49. (b) R.D. Adams J.E. Babin M. Tasi Organometallics 7 1988 503
50. (c) A.J. Deeming D.M. Speel Organometallics 16 1997 289
51. (d) D. Braga F. Grepioni P.J. Dyson B.F.G. Johnson C.M. Martin J. Chem. Soc. Dalton Trans. 1995 909
52. C.P. Horwitz D.F. Shriver Adv. Organomet. Chem. 23 1984 219
53. (a) A.J. Carty Adv. Chem. Ser. 196 1982 1963
54. (b) W.C. Mercer R.R. Whittle E.W. Burkhardt G.L. Geoffroy Organometallics 4 1985 68
55. (a) P. Nombel N. Lugan F. Mulla G. Lavigne Organometallics 13 1994 4673
56. (b) J.A. Cabeza I. del Río V. Riera S. Garca-Granda S.B. Sanni Organometallics 16 1997 1743
57. (c) P. Nombel N. Lugan B. Donnadieu G. Lavigne Organometallics 18 1999 187
58. J.S. Field R.J. Haines D.N. Smit J. Chem. Soc. Dalton Trans. 1988 1315
59. J.-S. Song G.L. Geoffroy A.L. Rheingold Inorg. Chem. 31 1992 1505
60. (a) M.J. McGlinchey tone J. Chem. Soc. Chem. Commun. 1970 1265
61. (b) W. Clegg G.M. Sheldrick D. Stalke S. Bhaduri K.S. Gopalkrishnan Acta Crystallogr. C40 1984 927
62. (c) See also: M.I. Bruce M.G. Humphrey O.B. Shawkataly M.R. Snow E.R.T. Tiekink J. Organomet. Chem. 315 1986 C51
63. (a) F. Iwasaki M.J. Mays P.R. Raithby P.L. Taylor P.J. Wheatley J. Organomet. Chem. 213 1981 185
64. (b) K. Natarajan O. Scheidsteger G. Huttner J. Organomet. Chem. 221 1981 301
65. (c) J.S. Field R.J. Haines D.N. Smit K. Natarajan O. Scheidsteger G. Huttner J. Organomet. Chem. 240 1982 C23
66. 4-bped) was analyzed anf found to display a bped-based π* LUMO at -10.47 eV
67. (a) D. Fenske A. Christidis Angew. Chem. Int. Ed. Engl. 20 1981 129
68. (b) F. Mao D.R. Tyler M.R.M. Bruce A.E. Bruce A.L. Rieger P.H. Rieger J. Am. Chem. Soc. 114 1992 6418
69. (c) D.M. Schut K.J. Keana D.R. Tyler P.H. Rieger J. Am. Chem. Soc. 117 1995 8939
70. (d) N.W. Duffy R.R. Nelson M.G. Richmond A.L. Rieger P.H. Rieger B.H. Robinson D.R. Tyler J.C. Wang K. Yang Inorg. Chem. 37 1998 4849
71. (a) M.B. Robin P. Day Adv. Inorg. Chem. Radiochem. 10 1967 247
72. (b) W. Kaim A. Klein M. Glöckle Acc. Chem. Res. 33 2000 755
73. - redox couple for bpcd, see: H.J. Becher D. Fenske M. Heymann Z. Anorg. Allg. Chem. 475 1981 27
74. (b) R. Meyer D.M. Schut K.J. Keana D.R. Tyler Inorg. Chim. Acta 240 1995 405
75. - redox couple for the dione ring it is sufficiently negative of the first reduction in cluster 3 so as to negate its involvement in the reduction process of 3
76. S.G. Bott J.C. Wang H. Shen M.G. Richmond J. Chem. Crystallogr. 29 1999 391
77. K. Yang S.G. Bott M.G. Richmond Organometallics 13 1994 3788