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Volumn 128, Issue 11, 2006, Pages 3831-3837

A two-photon antenna for photochemical delivery of nitric oxide from a water-soluble, dye-derivatized iron nitrosyl complex using NIR light

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CHROMOPHORES; DERIVATIVES; ESTERIFICATION; FLUORESCENCE; IRON; LASER PULSES; PHOTOCHEMICAL REACTIONS; PHOTONS;

EID: 33645460924     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057977u     Document Type: Article
Times cited : (119)

References (75)
  • 10
    • 0003764608 scopus 로고    scopus 로고
    • Ignarro, L. J., Ed.; Academic Press: San Diego, CA
    • (j) Nitric Oxide: Biology and Pathobiology; Ignarro, L. J., Ed.; Academic Press: San Diego, CA, 2000.
    • (2000) Nitric Oxide: Biology and Pathobiology
  • 34
    • 33645456134 scopus 로고    scopus 로고
    • note
    • 0 = the intensity of the incident light), the spatial selectivity is due to the highest probability of TPA being at the focal point of the excitation source.
  • 39
    • 33645460981 scopus 로고    scopus 로고
    • note
    • 11o
  • 71
    • 0032508693 scopus 로고
    • Albota, M.I. et al. Science 1988, 281, 1653-1656.
    • (1988) Science , vol.281 , pp. 1653-1656
    • Albota, M.I.1
  • 72
    • 33645453056 scopus 로고    scopus 로고
    • note
    • 3 clusters formed by NO photodissociation in competition to the fast back reaction with NO to regenerate the starting complex. Flash photolysis studies have confirmed this analysis. It is for this reason that luminescence measurements For the Roussin's salt esters with pendant chromophores are normally carried out in deaerated solutions in order to reduce the complications resulting from net photoreactions. However, when the goal is to evaluate the photoreaction chemistry itself, the photolyses are carried out in aerated solutions. Control experiments have demonstrated that the luminescence behavior of aerated and deaerated solutions of Fluor-RSE are initially equivalent; that is, there is no evidence of the luminescence being directly quenched or enhanced by the presence of dioxygen. The only effects in these cases are the results of different long-term stabilities of these solutions.
  • 74
    • 33645458311 scopus 로고    scopus 로고
    • note
    • a. Such considerations might have some modest impact upon Figure 5, thus explaining the slope slightly less than 2.0. However, the [NO] generated under TPE conditions is low, so that impact is likely to be minor.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.