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3 clusters formed by NO photodissociation in competition to the fast back reaction with NO to regenerate the starting complex. Flash photolysis studies have confirmed this analysis. It is for this reason that luminescence measurements For the Roussin's salt esters with pendant chromophores are normally carried out in deaerated solutions in order to reduce the complications resulting from net photoreactions. However, when the goal is to evaluate the photoreaction chemistry itself, the photolyses are carried out in aerated solutions. Control experiments have demonstrated that the luminescence behavior of aerated and deaerated solutions of Fluor-RSE are initially equivalent; that is, there is no evidence of the luminescence being directly quenched or enhanced by the presence of dioxygen. The only effects in these cases are the results of different long-term stabilities of these solutions.
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a. Such considerations might have some modest impact upon Figure 5, thus explaining the slope slightly less than 2.0. However, the [NO] generated under TPE conditions is low, so that impact is likely to be minor.
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