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+. 12
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note
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max at ∼354 nm (perhaps the result of further nitrite photoaquation).
-
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-
-
38
-
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0345178305
-
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note
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+.
-
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40
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42
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0344748155
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note
-
NO ≈ 0.1) 5b analogous conditions. The signals from I, however, decayed at rates faster than those generated by adding standard NO solutions, suggesting that decay processes other than autoxidation or diffusion from the solution are playing a role in this case.
-
-
-
-
43
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0344748154
-
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note
-
2+. 20c
-
-
-
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44
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0032578159
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0345178303
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Bakac, A.1
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46
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0344748153
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note
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-. 21b This point indeed was probed using negative ion electrospray mass spectroscopic analysis 18 of photolysis products of I in aerated aqueous solutions. Peaks for nitrate ion (the expected product of peroxynitrite rearrangement) were comparable in intensity to those for nitrite (the product of NO autoxidation), 21c suggesting that some NO was indeed trapped by superoxide. However, it should be emphasized that the major primary photoreaction is the high quantum yield transformation of I to IV, and flash and continuous photolysis evidence point convincingly to NO as the other primary photoproduct.
-
-
-
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48
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0027396852
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Ford, P.C.5
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