Photoreactivity of the ruthenium nitrosyl complex, Ru(salen)(Cl)(NO). Solvent effects on the back reaction of NO with the Lewis acid Ru(III)(salen)(Cl) [1]

Journal of the American Chemical Society

Volumn 122, Issue 31, 2000, Pages 7592-7593

  Works, Carmen F ^a   Ford, Peter C ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NITRIC OXIDE; RUTHENIUM DERIVATIVE;

CHEMICAL REACTION; COMPLEX FORMATION; LETTER; PHOTOREACTIVITY;

EID: 0034625887     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000137p     Document Type: Letter

References (25)

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19. 2.
20. 2 from air was used to make that reaction irreversible for spectral analysis,
21. (b) Light intensities for continuous photolysis experiments were determined using ferrioxalate actinometry according to: Calvert, J. G.; Pitts, J. N. Photochemistry; J. Wiley and Sons: New York, 1966.
22. (c) Flash experiments used time-resolved optical detection techniques described in ref 7.
23. Since both Co(TPP) and Co(TPP)NO absorb strongly in the photolysis wavelength regions, this experiment confirms NO formation but only qualitatively. We are currently working on reliable protocols for quantitative determination of very low NO concentrations in nonaqueous media.
24. 14b
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