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32
-
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33644934175
-
-
note
-
Determined by NOE analysis and by comparison with the analogous epoxide cyclopropanation product; see ref 13a.
-
-
-
-
33
-
-
33644962473
-
-
note
-
Use of LDA under these conditions gave 30% yield of amine 8.
-
-
-
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36
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0242558380
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39
-
-
33644949695
-
-
Isolated as a single diastereomer. Structure supported by X-ray crystallographic analysis: CCDC 292434 available at http://www.ccdc. cam.ac.uk.
-
-
-
-
40
-
-
33644951023
-
-
note
-
2, quenching directly after addition of the aziridine 9 (1 h) indicated incomplete reaction; 9 (52%), amine 10 (10%), and dimer 11 (22%) were obtained.
-
-
-
-
41
-
-
33644951694
-
-
note
-
Use of N-Ts aziridine 6 under these conditions gave a 47% yield of amine 8.
-
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43
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0030861104
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-
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33644937861
-
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note
-
2O) gave the bicyclic amine. (29) Determined by chiral GC analysis.
-
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45
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0001739961
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