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Volumn 67, Issue 7, 2002, Pages 2335-2344

Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C-silylaziridines - A cornucopia of highly selective transformations

(4) Aggarwal, Varinder K a Alonso, Emma a Ferrara, Marco a Spey, Sharon E b

a UNIVERSITY OF BRISTOL (United Kingdom)

b UNIVERSITY OF SHEFFIELD (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

STEREOGENIC CENTERS;

CARBON; DEUTERIUM; SUBSTITUTION REACTIONS;

ORGANIC COMPOUNDS;

1 TOSYL 2 BUTYL 3 TRIMETHYLSILYLAZIRIDINE DERIVATIVE; 1 TOSYL 2 PHENYL 3 TRIMETHYLSILYLAZIRIDINE DERIVATIVE; 2 BUTYLAZIRIDINE; ACETIC ACID; ALDEHYDE; ALPHA HYDROXYAZIRIDINE DERIVATIVE; AZIDE; AZIRIDINE DERIVATIVE; AZIRINE DERIVATIVE; BETA LACTAM; CADMIUM CHLORIDE; CARBON; CARBONYL DERIVATIVE; CHLORIDE; DEUTERIUM; DIAZOMETHANE; ESTER; FLUORIDE; FUSED HETEROCYCLIC RINGS; IMINE; LITHIUM DERIVATIVE; METHYL IODIDE; ORGANOMETALLIC COMPOUND; PHENYL GROUP; PHOSPHATE; THIOL DERIVATIVE; TRIMETHYLSILYL DERIVATIVE; TRIMETHYLSILYLDIAZOMETHANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CIS ISOMER; CRYSTAL STRUCTURE; DIASTEREOISOMER; ELECTRON; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS; TRANS ISOMER; X RAY ANALYSIS;

EID: 0037023469 PISSN: 00223263 EISSN: None Source Type: Journal
DOI: 10.1021/jo016312h Document Type: Article

Times cited : (116)

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