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33644908429
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[15]
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40
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4444384013
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44
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33644929933
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note
-
12 were investigated once the corresponding tetrarosettes were fully formed (see text for direct method synthesis).
-
-
-
-
45
-
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33644893293
-
-
note
-
12.
-
-
-
-
46
-
-
33644902867
-
-
note
-
When the chiral centers are in the cyanurate building blocks, a center with R stereochemistry generally induces the formation of assemblies with P helicity. Thus, when (R)-MePheCYA is present the formation of the M diastereomer is unfavorable.
-
-
-
-
47
-
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33644882181
-
-
note
-
The kinetic model was implemented in MicroMath® Scientist® for Windows, version 2.01. However, an internal error of the software precluded the possibility to use this software and therefore the model.
-
-
-
-
48
-
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33644923731
-
-
note
-
Negative cooperativity in assemblies formed with tetramelamine 1b means that formation of the first double rosette disfavors the formation of the second double rosette, while positive cooperativity in assemblies formed with tetramelamine 1a means that formation of the first double rosette favors the formation of the whole assembly.
-
-
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49
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0037123770
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