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Volumn 12, Issue 9, 2006, Pages 2630-2638

Amplification of chirality in hydrogen-bonded tetrarosette helices

Author keywords

Chiral amplification; Hydrogen bonds; Self assembly; Supramolecular chirality

Indexed keywords

FREE ENERGY; SELF ASSEMBLY; THERMODYNAMICS;

EID: 33644906613     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200501161     Document Type: Article
Times cited : (20)

References (49)
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    • Angew. Chem. Int. Ed. 1999, 38, 3418-3438;
    • (1999) Angew. Chem. Int. Ed. , vol.38 , pp. 3418-3438
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    • 0033517692 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1999, 38, 3138-3154.
    • (1999) Angew. Chem. Int. Ed. , vol.38 , pp. 3138-3154
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    • 0032538773 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1998, 37, 2922-2959.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 2922-2959
  • 17
    • 33644918805 scopus 로고    scopus 로고
    • (Eds.; N. Berova, K. Nakanishi, R. W. Woody), Wiley, New York, Chapter 17
    • For examples of amplification of chirality in covalent polymers: a) M. M. Green, in Circular Dichroism: Principles and Applications, 2nd ed, (Eds.; N. Berova, K. Nakanishi, R. W. Woody), Wiley, New York, 2000, Chapter 17;
    • (2000) Circular Dichroism: Principles and Applications, 2nd Ed
    • Green, M.M.1
  • 39
    • 33644908429 scopus 로고    scopus 로고
    • note
    • [15]
  • 44
    • 33644929933 scopus 로고    scopus 로고
    • note
    • 12 were investigated once the corresponding tetrarosettes were fully formed (see text for direct method synthesis).
  • 45
    • 33644893293 scopus 로고    scopus 로고
    • note
    • 12.
  • 46
    • 33644902867 scopus 로고    scopus 로고
    • note
    • When the chiral centers are in the cyanurate building blocks, a center with R stereochemistry generally induces the formation of assemblies with P helicity. Thus, when (R)-MePheCYA is present the formation of the M diastereomer is unfavorable.
  • 47
    • 33644882181 scopus 로고    scopus 로고
    • note
    • The kinetic model was implemented in MicroMath® Scientist® for Windows, version 2.01. However, an internal error of the software precluded the possibility to use this software and therefore the model.
  • 48
    • 33644923731 scopus 로고    scopus 로고
    • note
    • Negative cooperativity in assemblies formed with tetramelamine 1b means that formation of the first double rosette disfavors the formation of the second double rosette, while positive cooperativity in assemblies formed with tetramelamine 1a means that formation of the first double rosette favors the formation of the whole assembly.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.