Chiral studies across the spectrum of polymer science

Accounts of Chemical Research

Volumn 34, Issue 8, 2001, Pages 672-680

  Green, M M ^a   Cheon, K S ^a   Yang, S Y ^a   Park, J W ^a   Swansburg, S ^a   Liu, W ^a  

^a POLYTECHNIC UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPOLYMER; POLYMER;

ARTICLE; CHIRALITY; COMPLEX FORMATION; HYDROPHOBICITY; MOLECULAR MODEL; OPTICAL ROTATION; POLYMERIZATION; PROTEIN DENATURATION; RACEMIC MIXTURE; STEREOCHEMISTRY;

EID: 0034873438     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar010009l     Document Type: Article

References (56)

1. Techniques for the study of biological structure and function
2. The Kinetics of protein denaturation. I. The behavior of the optical rotation of ovalbumin in urea solutions
3. Optical rotation and polypeptide chain configuration in proteins
4. Poly-γ-benzyl-L-glutamate: The helix-coil transition in solution
5. Optical rotatory dispersion of sperm whale ferrimyoglobin and horse ferrihemoglobin
6. Formation and stabilization of the collagen-fold
7. The optical rotation and molecular configuration of synthetic polypeptides in dilute solution
8. The configurational changes of poly-L-proline in solution
9. The stereochemistry of linear macromolecules
10. Stereospecific olefin polymerization with chiral metallocene catalysts
11. 3 symmetry
12. Foldamer-based molecular recognition
13. Foldamers: A Manifesto
14. Crystal structure of form II of syndiotactic poly(1-butene)
15. Helical superstructures from charged poly(styrene)-poly(isocyanodipeptide) block copolymers
16. The macromolecular route to chiral amplification
17. A model for how polymers amplify chirality
18. A helical polymer with a cooperative response to chiral information
19. Macromolecular stereochemistry: A cooperative deuterium isotope effect leading to a large optical rotation
20. Macromolecular stereochemistry: The out-of-proportion influence of optically active comonomers on the conformational characteristics of polyisocyanates: The sergeants and soldiers experiment
21. Macromolecular stereochemistry: Helical sense preference in optically active polyisocyanates. Amplification of a conformational equilibrium deuterium isotope effect
22. Molecular weight dependence of the optical rotation of poly((R)-1-deuterio-n-hexyl isocyanate) in dilute solution
23. Hydration forces between phospholipid bilayers
24. A macromolecular conformational change driven by a minute chiral solvation energy
25. Chiral solvation as a means to quantitatively characterize preferential solvation of a helical polymer in mixed solvents
26. Majority rules in the copolymerization of mirror image isomers
27. Switching a helical polymer between mirror images using circularly polarized light
28. Theory of chiral order in random copolymers
29. Designing a helical polymer that reverses handedness at a selected, continuously variable temperature
30. Mechanism of the transformation of a stiff polymer lyotropic nematic liquid crystal to the cholesteric state by dopant mediated chiral information transfer
31. Molecular weight of polyacrylic and polymethacrylic acid
32. The titration of polymeric acids
33. Potentiometric behavior of polymethacrylic acid
34. The models of the denaturation of globular proteins. II. Hydrophobic interactions and conformational transition in polymethacrylic acid
35. Time-resolved fluorescence study of chain dynamics. 1. Poly(methacrylic acid) in dilute water solutions
36. Study of the equilibrium and the kinetics of the fluorescence enhancement on mixing solutions of auramine O and poly(methacrylic acid)
37. An on/off circular dichroism signal reveals a pH dependent competition between a cyclodextrin and a polyelectrolyte for an atropisomeric aromatic guest
38. Materials-chirality: The attempt to design an intermolecular transfer of a dye molecule between a chiral and an achiral environment
39. Clustering of poly(methacrylic acid) around appended binaphthyl labels as reflected by the disruption of γ-cyclodextrin complexation and racemization kinetics
40. Nature of the "hypercoiled" form of poly(methacrylic acid) in water at low pH
41. Photoinitiation and hydrophobic cluster formation in poly(methacrylic acid)
42. Supercooled liquids and glasses
43. Size dependence of tracer diffusion in supercooled liquids
44. Rate-memory and dynamic heterogeneity of first-order reactions in a polymer matrix
45. Chiral studies in amorphous solids: The effect of the polymeric glassy state on the racemization kinetics of bridged paddled binaphthyls
46. Geometric isomerization vs. cycloreversion in the pyrolysis of tetramethylcyclobutane-d6. Ponderal and energetic effects on the competition ratio in a series of "1,4-butanediyls"
47. Dynamics of atropisomerization of 1,1′-binaphthyl in several nematic solvents. Rate enhancement by a solid phase
48. Glassy state and secondary structures of chiral macromolecules: Polyisocyanates and polyketones
49. Holograms can store terabytes, but where?