메뉴 건너뛰기




Volumn , Issue 11, 2000, Pages 887-892

Chiral autocatalysis: Where stereochemistry meets the origin of life

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CHIRALITY; CRYSTALLIZATION; ENANTIOMER; NONHUMAN; REVIEW; STEREOCHEMISTRY;

EID: 0034616834     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a908300f     Document Type: Review
Times cited : (184)

References (69)
  • 13
    • 0007995593 scopus 로고    scopus 로고
    • ed. D. B. Cline, American Institute of Physics, Woodbury, NY
    • A. J. MacDermott, in Physical Origin of Homochirality in Life, ed. D. B. Cline, American Institute of Physics, Woodbury, NY, 1996, pp. 241-254.
    • (1996) Physical Origin of Homochirality in Life , pp. 241-254
    • MacDermott, A.J.1
  • 45
    • 0343446584 scopus 로고    scopus 로고
    • personal communication (to P. C.)
    • K. Soai, personal communication (to P. C.)
    • Soai, K.1
  • 63
    • 0033543477 scopus 로고    scopus 로고
    • A particular case of spontaneous resolution involves achiral compounds having chiral conformations, which maybe 'frozen' in the solid state or in solution at low temperature. Thus, enantiomeric crystals of an N-methylbenzamide, which correspond to a stable anti conformer, could be distinguished morphologically as in Pasteur's experiments. Moreover, slow crystallization may lead to homochiral crystals. All four molecules in the unit cell of the chiral crystal have the same chirality. See for instance: I. Azumaya, I. Okamoto, S. Nakayama, A. Tanatani, K. Yamaguchi, K. Shudo and H. Kagechika, Tetrahedron, 1999, 55, 11237.
    • (1999) Tetrahedron , vol.55 , pp. 11237
    • Azumaya, I.1    Okamoto, I.2    Nakayama, S.3    Tanatani, A.4    Yamaguchi, K.5    Shudo, K.6    Kagechika, H.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.