SCOPUS 정보 검색 플랫폼

Journal of Photochemistry and Photobiology A: Chemistry

Volumn 178, Issue 2-3 SPEC. ISS., 2006, Pages 130-139

Excitation energy migration in a dodecameric porphyrin box

(8) Hwang, In Wook a,d Yoon, Zin Seok a Kim, Jiwon b Kamada, Taisuke c Ahn, Tae Kyu a Aratani, Naoki c Osuka, Atsuhiro c Kim, Dongho a

a Yonsei University (South Korea)

b Korea Advanced Institute of Science and Technology (KAIST) (South Korea)

c KYOTO UNIVERSITY (Japan)

d UNIVERSITY OF CALIFORNIA (United States)

Author keywords

Coupling energy matrix; Excitation energy hopping (EEH); Exciton coupling; Exciton exciton annihilation; Self assembled porphyrin array; Transient absorption anisotropy (TAA)

Indexed keywords

EID: 33144456155 PISSN: 10106030 EISSN: None Source Type: Journal
DOI: 10.1016/j.jphotochem.2005.10.029 Document Type: Article

Times cited : (12)

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- -1. Among these, only -85, -139, and six zeros can be determined to be dark states (-85, -139) or noninteracting (six zeros), but the other four eigenvalues, -44, -269, 93, 444 cannot be determined to be either allowed or forbidden transition due to the complicated eigenvectors in the analysis of the eigenvalues. However, according to the absorption spectrum, the interaction among the transition dipoles of x or y axis is estimated to be apparently small. As a result, regardless of the allowed or forbidden transition of interacting x and y axis', the dipole coupling energies in x and y axis' are small enough to be ignored, because the excitonic state formed by transition dipole coupling in x and y axis' cannot be observed in UV absorption spectrum or calculated by diagonalization of interacting matrices.

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