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The preparation and characterization of compound 2 is described in the supporting information.
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9544251701
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The redox potentials for 1 and 2 were determined by cyclic voltammetry at a Pt electrode in butyronitrile containing 0.1 M tetra-n-butylammonium perchlorate. The one-electron oxidation potential of ANI in both 1 and 2 is 1.19 V, while the one-electron reduction potential of NI in 1 is -0.54 V, and those of NI and PI in 2 are -0.40 and -0.74 V, respectively (all vs SCE).
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29
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9544250687
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note
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The probe spot size is kept smaller than either of the two pump beams, and all three beams are overlapped inside a 1-mm-path-length stirred sample.
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