Tertiary phosphine ligand-exchange reactions involving the M(Strictly equivalent to)M quadruply bonded complexes M2Cl4L4, where L = PMe3, PEt3, PBun3 or PMe2Ph

Journal of the Chemical Society - Dalton Transactions

Volumn , Issue 16, 1997, Pages 2735-2743

  Chisholm, Malcolm H ^a   McInnes, Jacqueline M ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33749103800     PISSN: 03009246     EISSN: None     Source Type: Journal    
DOI: 10.1039/a701222e     Document Type: Article

References (33)

1. F. A. Cotton and R. W. Walton, in Multiple Bonds between Metal Atoms, Oxford University Press, 2nd edn., 1993.
2. T. A. Budzichowski, M. H. Chisholm and K. Folting, Chem. Eur. J., 1996, 2, 110 and refs. therein.
3. S. A. Best, T. J. Smith and R. A. Walton, Inorg. Chem., 1978, 17, 99;
4. P. A. Agaskar, F. A. Cotton, D. R. Derringer, G. L. Powell, D. R. Root and T. J. Smith. Inorg. Chem., 1985, 44, 2786;
5. M. Bakir, F. A. Cotton, L. R. Falvelo, C. Q. Simpson and R. A. Walton, Inorg. Chem, 1988, 27, 4197.
6. F. L. Campbell, III, F. A. Cotton and T. L. Netzel, Inorg. Chem., 1985, 24, 177.
7. F. A. Cotton and S. Kitagawa, Polyhedron, 1988, 7, 463;
8. A. McVilie and R. D. Peacock, Polyhedron, 1992, 11, 2531;
9. P. A. Agaskar and F. A. Cotton, Inorg. Chem., 1986, 25, 15;
10. R. H. Cayton and M. H. Chisholm, Inorg. Chem., 1991, 30, 1422.
11. J. M. Casas, R. H. Cayton and M. H. Chisholm, Inorg. Chem., 1991, 30, 360.
12. F. Basolo and R. G. Pearson, in Mechanisms of Inorganic Ractions. A study of Metal Complexes in Solution, Wiley, New York, 2nd edn., 1968.
13. H. Chen and F. A. Cotton. Polyhedron, 1995, 14, 2221.
14. R. H. Cayton, S. T. Chacon, M. H. Chisholm and K. Folting, Polyhedron, 1993, 12, 415.
15. (a) G. S. Girolami, V. V. Mainz, R. A. Andersen, S. H. Vollmer and V. W. Day, J. Am. Chem. Soc. 1981, 103, 3952;
16. (b) G. S. Girolami, V. V. Mainz and R. A. Andersen, J. Am. Chem. Soc., 1982, 104, 2041.
17. C. Darwin, in The Autobiography of Charles Danvin, ed. N. Barlow, W. W. Norton and Co., New York and London, 1958, p. 84.
18. See, for example, R. L. Luck, R. H. Morris and J. F. Sawyer, Inorg. Chem., 1987, 26, 2422;
19. R. H. Morris, Polyhedron, 1987, 6, 793.
20. T. G. Appleton, H. C. Clark and L. E. Manzer, Coord. Chem. Rev., 1973, 10, 335.
21. V. Riena, M. A. Ruiz, F. Villafane, C. Bois and Y. Jeanin, J. Organomet. Chem., 1990, 382, 407;
22. F. A. Cotton and M. Matsusz, Polyhedron, 1987, 6, 261 and refs. therein.
23. J. San Filippo, jun., H. J. Sniadock and R. L. Grayson, Inorg. Chem., 1974, 13, 2121;
24. J. San Filippo and M. A. Schaefer-King, Inorg. Chem., 1976, 15, 1228.
25. C. A. Tolman, Chem. Rev., 1977, 77, 313.
26. n binding see ref. 2;
27. - binding: T. A. Budzichowski and M. H. Chisholm, Polyhedron, 1994, 13, 2035.
28. D. Neuhaus and M. Williamson, The Nuclear Overhauser Effect in Structural and Conformational Analysis, VCH, Weinheim, 1989.
29. J. E. Finholt, P. Leupin and A. G. Sykes, Inorg. Chem., 1983, 22, 3315.
30. See ref. 7, ch. 5 and the search for the D mechanism, in M. L. Tobe, Inorganic Reaction Mechanisms, Nelson Publishers, London, 1972, pp. 63-66.
31. M. L. H. Green, G. Parkin, J. Bashkin, J. Fail and K. Prout, J. Chem. Soc., Dalton Trans., 1982, 2519;
32. F. A. Cotton, J. Czuchajowska and R. L. Luck, J. Chem. Soc., Dalton Trans., 1991, 579.
33. R. R. Schrock, L. G. Sturgeoff and P. R. Sharp, Inorg. Chem., 1983, 22, 2801.