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Volumn 690, Issue 20 SPEC. ISS., 2005, Pages 4505-4516

Supraphos: A supramolecular strategy to prepare bidentate ligands

Author keywords

Allylic substitution; Catalysis; Combinatorial chemistry; Hydroformylation; Palladium; Supramolecular chemistry

Indexed keywords

ALKYLATION; CATALYSIS; CATALYSTS; CHELATION; ORGANOMETALLICS; PALLADIUM; PHOSPHORUS COMPOUNDS; PORPHYRINS; RHODIUM COMPOUNDS; ZINC COMPOUNDS;

EID: 27144450668     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.02.026     Document Type: Conference Paper
Times cited : (56)

References (64)
  • 2
    • 0003445429 scopus 로고    scopus 로고
    • E.N. Jacobsen A. Pfaltz H. Yamamoto Springer Berlin
    • J.M. Brown E.N. Jacobsen A. Pfaltz H. Yamamoto Comprehensive asymmetric catalysis vol. 1 1999 Springer Berlin (Chapter 5.1)
    • (1999) Comprehensive Asymmetric Catalysis , vol.1
    • Brown, J.M.1
  • 36
    • 1542581810 scopus 로고
    • G.R. Newkome Chem. Rev. 93 1993 2067 and references cited therein
    • (1993) Chem. Rev. , vol.93 , pp. 2067
    • Newkome, G.R.1
  • 41
    • 27144527412 scopus 로고    scopus 로고
    • note
    • 3-Pyridylmethyldiphenylphosphine and imidazol-1-yl- methyldiphenylphosphine were kindly donated by Shell Research and Technology center, Amsterdam, The Netherlands.
  • 46
    • 27144452132 scopus 로고    scopus 로고
    • note
    • P-PO3 = 111 Hz) suggests that phosphite coordination to the rhodium is at the equatorial and apical position in fast exchange on the NMR spectroscopy time-scale. The phosphorus-signal of the phosphite is at rather low field (δ = 179.8 ppm) which is attributed to steric constraints, as is also found for several other phosphine-phosphite rhodium complexes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.