Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex

Journal of the American Chemical Society

Volumn 127, Issue 40, 2005, Pages 13760-13761

  Takita, Ryo ^a   Yakura, Kenichiro ^a   Ohshima, Takashi ^a,b   Shibasaki, Masakatsu ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2,2' DIHYDROXY 1,1' BINAPHTHYL; ALDEHYDE; CYCLOHEXANE; CYCLOHEXANE CARBOXALDEHYDE; INDIUM; ISOVALERALDEHYDE; PHENYLACETYLENE; UNCLASSIFIED DRUG;

ALKYNYLATION; ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; ENANTIOSELECTIVITY; POLYMERIZATION; REACTION TIME;

ALDEHYDES; ALKYNES; CATALYSIS; INDIUM; MOLECULAR STRUCTURE; NAPHTHOLS; ORGANOMETALLIC COMPOUNDS;

EID: 26444539787     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja053946n     Document Type: Article

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42. The monometallic mechanism cannot be completely excluded by only positive nonlinear effects. For the proposed bimetallic or monometallic mechanism, see Supporting Information.