Iridabenzenes from iridacyclopentadienes: Unusual C - C bond formation between unsaturated hydrocarbyl ligands

Organometallics

Volumn 24, Issue 20, 2005, Pages 4849-4852

  Chin, Chong Shik ^a   Lee, Hyungeui ^a   Bum, Min Sik ^a  

^a Sogang University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; ORGANOMETALLICS;

ALKYNYL LIGANDS; C-C COUPLINGS; IRIDABENZENES; PROTONATION;

BENZENE;

EID: 26444452001     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050529a     Document Type: Article

References (33)

1. (a) Lautens, M.; Klute, W.; Tam, W. Chem. Rev. 1996, 96, 49.
2. (b) Saito, S.; Yamamoto, Y. Chem. Rev. 2000, 100, 2901.
3. (c) Burrows, A. D.; Green, M.; Jeffery, J. C.; Lynam, J. M.; Mahon, M. F. Angew. Chem., Int. Ed. 1999, 38, 3043.
4. (a) Barrio, P.; Esteruelas, M. A.; Oñate, E. J. Am. Chem. Soc. 2004, 126, 1946.
5. (b) Xia, H.; He, G.; Zhang, H.; Wen, T. B.; Sung, H. H. Y.; Williams, I. D.; Jia, G. J. Am. Chem. Soc. 2004, 126, 6862.
6. (c) Paneque, M.; Posadas, C. M.; Poveda, M. L.; Rendón, N.; Salazar, V.; Oñate, E.; Mereiter, K. J. Am. Chem. Soc. 2003, 125, 9898.
7. (d) Wen, T. B.; Zhou, Z. Y.; Jia, G. Angew. Chem., Int. Ed. 2001, 40, 1951.
8. (e) Wen, T. B.; Ng, S. M.; Houg, W. Y.; Zhou, Z. Y.; Lo, M. F.; Shek, L.-Y.; Williams, I. D.; Lin, Z.; Jia, G. J. Am. Chem. Soc. 2003, 125, 884.
9. Chin, C. S.; Lee, H. Chem. Eur. J. 2004, 10, 4518.
10. Bleeke, J. R.; Xie, Y.-F.; Peng, W.-J.; Chiang, M. J. Am. Chem. Soc. 1989, 111, 4118.
11. (a) Chin, C. S.; Lee, H.; Noh, S.; Park, H.; Kim, M. Organometallics 2003, 22, 2119.
12. (b) Chin, C. S.; Kim, M.; Lee, H. Organometallics 2002, 21,1679.
13. (c) Chin, C. S.; Cho, H.; Won, G.; Oh, M.; Ok, K. M. Organometallics 1999, 18, 4810.
14. (d) Chin, C. S.; Lee, H.; Park, H.; Kim, M. Organometallics 2002, 21, 3889.
15. (e) Chin, C. S.; Kim, M.; Lee, H.; Noh, S.; Ok, K. M. Organometallics 2002, 21, 4785.
16. (f) Chin, C. S.; Won, G.; Chong, D.; Kim, M.; Lee, H. Acc. Chem. Res. 2002, 35, 218.
17. (g) Chin, C. S.; Kim, M.; Won, G.; Jung, H.; Lee, H. Dalton Trans. 2003, 2325.
18. (h) Chin, C. S.; Maeng, W.; Chong, D.; Won, G.; Lee, B.; Park, Y. J.; Shin, J. M. Organometallics 1999, 18, 2210.
19. (i) Werner, H.; Ilg, K.; Weberndörfer, B. Organometallics 2000, 19, 3145.
20. (j) Jiménez-Tenorio, M. A.; Jiménez-Tenorio, M.; Puerta, M. C.; Valerga, P. Organometallics 2000, 19, 1333.
21. (k) Yang, J.-Y.; Huang, S.-L.; Lin, Y.-C.; Liu, Y.-H.; Wang, Y. Organometallics 2000, 19, 269.
22. (l) Bohana, C.; Buil, M. L.; Esteruelas, M. A.; Oñate, E.; Valero, C. Organometallics 1999, 18, 5176.
23. Bianchini, C.; Mantovani, N.; Marchi, A.; Marvelli, L.; Masi, D.; Peruzzini, M.; Rossi, R.; Romerosa, A. Organometallics 1999, 18, 4501.
24. (n) Slugovc, C.; Mereiter, K; Schmid, R.; Kirchner, K. J. Am. Chem. Soc. 1998, 120, 6175.
25. (o) Huang, D.; Oliván, M.; Huffman, J. C.; Eisenstein, O.; Caulton, K. G. Organometallics 1998, 17, 4700.
26. (p) O'Connor, J. M.; Hiibner, K; Merwin, R.; Gantzel, P. K.; Fong, B. S. J. Am. Chem. Soc. 1997, 119, 3631.
27. (q) Ipaktschi, J.; Mirzaei, F.; Demuth-Eberle, G. J.; Beck, J.; Serafin, M. Organometallics 1997, 16, 3965.
28. (r) Yang, S.-M.; Chan, M. C.-W.; Cheung, K.-K; Che, C.-M.; Peng, S.-M. Organometallics 1997, 16, 2819.
29. (s) Bianchini, C.; Innocenti, P.; Peruzzini, M.; Romerosa, A.; Zanobini, F. Organometallics 1996, 15, 272.
30. + in the presence of RC≡CH (3 equiv) produce a mixture of iridabenzene 6 and unknown iridium complex(es), and a small amount of 1,3-butadiene.
31. (a) Ara, I.; Berenguer, J. R.; Eguizábal, E.; Forniés, J.; Lalinde, E.; Martínez, F. Organometallics 1999, 18, 4344.
32. (b) Ara, I.; Berenguer, J. R.; Eguizábal, E.; Forniés, J.; Lalinde, E.; Martín, A.; Martínez, F. Organometallics 1998, 17, 4578.
33. (c) Fernández, F. J.; Alfonso, M.; Schmalle, H. W.; Berke, H. Organometallics 2001, 20, 3122.