Protonation and bromination of an osmabenzyne: Reactions leading to the formation of new metallabenzynes

Journal of the American Chemical Society

Volumn 125, Issue 4, 2003, Pages 884-885

  Wen, Ting Bin ^a   Ng, Sze Ming ^a   Hung, Wai Yiu ^a   Zhou, Zhong Yuan ^b   Lo, Man Fung ^a   Shek, Lai Yung ^a   Williams, Ian D ^a   Lin, Zhenyang ^a   Jia, Guochen ^a  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^b HONG KONG POLYTECHNIC UNIVERSITY   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE DERIVATIVE; BROMINE; METALLABENZYNE DERIVATIVE; OSMABENZYNE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BROMINATION; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON TRANSPORT; SUBSTITUTION REACTION; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037471637     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029110r     Document Type: Article

References (24)

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9. For additional examples of recent work on metallabenzenes, see: (a) Wu, H. P.; Lanza, S.; Weakley, T. J.; Haley, M. M. Organometallics 2002, 21, 2824. (b) Jacob, V.; Weakley, T. J. R.; Haley, M. M. Angew. Chem., Int. Ed. 2002, 41, 3470. (c) Gilbertson, R. D.; Weakley, T. J. R.; Haley, M. M. J. Am. Chem. Soc. 1999, 121, 2597. (d) Englert, U.; Podewils, F.; Schiffers, I.; Salzer, A. Angew. Chem. Int. Ed. 1998, 37, 2134. (e) Bleeke, J. R.; Behm, R. J. Am. Chem. Soc. 1997, 119, 8503. (f) Bleeke, J. R.; Behm, R.; Xie, Y. F.; Chiang, M. Y.; Robinson, K. D.; Beatty, A. M. Organometallics 1997, 16, 606 and references therein.
10. For additional examples of recent work on metallabenzenes, see: (a) Wu, H. P.; Lanza, S.; Weakley, T. J.; Haley, M. M. Organometallics 2002, 21, 2824. (b) Jacob, V.; Weakley, T. J. R.; Haley, M. M. Angew. Chem., Int. Ed. 2002, 41, 3470. (c) Gilbertson, R. D.; Weakley, T. J. R.; Haley, M. M. J. Am. Chem. Soc. 1999, 121, 2597. (d) Englert, U.; Podewils, F.; Schiffers, I.; Salzer, A. Angew. Chem. Int. Ed. 1998, 37, 2134. (e) Bleeke, J. R.; Behm, R. J. Am. Chem. Soc. 1997, 119, 8503. (f) Bleeke, J. R.; Behm, R.; Xie, Y. F.; Chiang, M. Y.; Robinson, K. D.; Beatty, A. M. Organometallics 1997, 16, 606 and references therein.
11. For additional examples of recent work on metallabenzenes, see: (a) Wu, H. P.; Lanza, S.; Weakley, T. J.; Haley, M. M. Organometallics 2002, 21, 2824. (b) Jacob, V.; Weakley, T. J. R.; Haley, M. M. Angew. Chem., Int. Ed. 2002, 41, 3470. (c) Gilbertson, R. D.; Weakley, T. J. R.; Haley, M. M. J. Am. Chem. Soc. 1999, 121, 2597. (d) Englert, U.; Podewils, F.; Schiffers, I.; Salzer, A. Angew. Chem. Int. Ed. 1998, 37, 2134. (e) Bleeke, J. R.; Behm, R. J. Am. Chem. Soc. 1997, 119, 8503. (f) Bleeke, J. R.; Behm, R.; Xie, Y. F.; Chiang, M. Y.; Robinson, K. D.; Beatty, A. M. Organometallics 1997, 16, 606 and references therein.
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24. In the B3LYP calculations, Lan2dz was used for Os, P, and Cl, while 6-31G was used for all other atoms. Polarization functions were added for Cl (ζ = 0.514), P (ζ = 0.34), and Si (ζ = 0.262).