Propene polymerization using ansa-metallocenium ions: Catalyst deactivation processes during monomer consumption and molecular structures of the products formed

Polyhedron

Volumn 24, Issue 11, 2005, Pages 1234-1249

  Al Humydi, Abdulaziz ^a   Garrison, Jered C ^b   Mohammed, Muqtar ^c   Youngs, Wiley J ^b   Collins, Scott ^a  

^a The University of Akron   (United States)

^b UNIVERSITY OF AKRON   (United States)

^c UNIVERSITY OF WATERLOO   (Canada)

Author keywords

Borohydride complexes; C H activation; Metallocene; Polymerization

Indexed keywords

EID: 22744458923     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2005.02.005     Document Type: Article

References (91)

1. M. Bochmann, S.J. Lancaster, M.D. Hannant, A. Rodriguez, M. Schormann, D.A. Walker, and T.J. Woodman Pure Appl. Chem. 75 2003 1183
2. E.X.-Y. Chen, and T.J. Marks Chem. Rev. 100 2000 1391
3. For recent quenched flow kinetic and related mechanistic studies on olefin polymerization using discrete ion-pairs, see C.R. Landis, D.R. Sillars, and J.M. Batterton J. Am. Chem. Soc. 126 2004 8890
4. A. Rodriguez-Delgado, M.D. Hannant, S.J. Lancaster, and M. Bochmann Macromol. Chem. Phys. 205 2004 334
5. F. Song, R.D. Cannon, and M. Bochmann Chem. Commun. 2004 542
6. F. Song, M.D. Hannant, R.D. Cannon, and M. Bochmann Macromol. Symp. 213 2004 173
7. D.R. Sillars, and C.R. Landis J. Am. Chem. Soc. 125 2003 9894
8. C.R. Landis, K.A. Rosaaen, and D.R. Sillars J. Am. Chem. Soc. 125 2003 1710
9. C.R. Landis, K.A. Rosaaen, and J. Uddin J. Am. Chem. Soc. 124 2002 12062
10. Z. Liu, E. Somsook, C.B. White, K.A. Rosaaen, and C.R. Landis J. Am. Chem. Soc. 123 2001 11193
11. Z. Liu, E. Somsook, C. White, and C.R. Landis J. Am. Chem. Soc. 123 2001 2915
12. J. Zhou, S.J. Lancaster, D.A. Walker, S. Beck, M. Thornton-Pett, and M. Bochmann J. Am. Chem. Soc. 123 2001 223
13. M. Chen, J.A. Roberts, and T.J. Marks J. Am. Chem. Soc. 126 2004 4605
14. V. Busico, R. Cipullo, F. Cutillo, M. Vacatello, and V. Van Axel Castelli Macromolecules 36 2003 4258
15. M. Mohammed, M. Nele, A. Al-Humydi, S. Xin, R. Stapleton, and S. Collins J. Am. Chem. Soc. 125 2003 7930
16. M. Mohammed, S. Xin, M. Nele, A. Al-Humydi, and S. Collins Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 43 2002 305
17. M. Chen, and T.J. Marks J. Am. Chem. Soc. 123 2001 11803
18. E. Chen, M.V. Metz, L. Li, C.L. Stern, and T.J. Marks J. Am. Chem. Soc. 120 1998 6287
19. J.C. Chien, W. Song, and M.D. Rausch J. Polym. Sci. A 32 1994 2387
20. J. Ewen K. Soga M. Terano Catalyst design for tailor-made polyolefins 1994 Elsevier Tokyo 405
21. J.C. Chien, W. Song, and M.D. Rausch Macromolecules 26 1993 3239
22. N. Herfert, and G. Fink Makromol. Chem., Rapid Commun. 14 1993 91
23. M.A. Giardello, M.S. Eisen, C.L. Stern, and T.J. Marks J. Am. Chem. Soc. 115 1993 3326
24. For recent theoretical work incorporating the counter-anion, see K. Vanka, Z. Xu, and T. Ziegler Macromol. Symp. 213 2004 275
25. K. Vanka, Z. Xu, and T. Ziegler Organometallics 23 2004 2900
26. Z. Xu, K. Vanka, and T. Ziegler Macromol. Symp. 206 2004 457
27. K. Vanka, Z. Xu, and T. Ziegler Can. J. Chem. 81 2003 1413
28. Z. Xu, K. Vanka, and T. Ziegler Organometallics 23 2004 104
29. K. Vanka, Z. Xu, and T. Ziegler Israel J. Chem. 42 2003 403
30. Z. Xu, K. Vanka, T. Firman, A. Michalak, E. Zurek, C. Zhu, and T. Ziegler Organometallics 21 2002 2444
31. G. Lanza, I.L. Fragala, and T.J. Marks Organometallics 21 2002 5594
32. G. Lanza, I.L. Fragala, and T.J. Marks Organometallics 20 2001 4006
33. G. Lanza, I.L. Fragala, and T.J. Marks J. Am. Chem. Soc. 122 2000 12764
34. G. Lanza, I.L. Fragala, and T.J. Marks J. Am. Chem. Soc. 120 1998 8257
35. M. Chen, J.A. Roberts, and T.J. Marks Organometallics 23 2004 932
36. S.J. Lancaster, A. Rodriguez, A. Lara-Sanchez, M.D. Hannant, D.A. Walker, D.H. Hughes, and M. Bochmann Organometallics 21 2002 451
37. R.E. LaPointe, G.R. Roof, K.A. Abboud, and J. Klosin J. Am. Chem. Soc. 122 2000 9560
38. V.C. Williams, G.J. Irvine, W.E. Piers, Z. Li, S. Collins, W. Clegg, M.R.J. Elsegood, and T.B. Marder Organometallics 19 2000 1619
39. V.C. Williams, C. Dai, Z. Li, S. Collins, W.E. Piers, W. Clegg, M.R.J. Elsegood, and T.B. Marder Angew. Chem., Int. Ed. 38 1999 3695
40. S.J. Lancaster, D.A. Walker, M. Thornton-Pett, and M. Bochmann Chem. Commun. 1999 1533
41. K. Koehler, W.E. Piers, A.P. Jarvis, S. Xin, Y. Feng, A.M. Bravakis, S. Collins, W. Clegg, G.P.A. Yap, and T.B. Marder Organometallics 17 1998 3557
42. L. Jia, X. Yang, C. Stern, and T.J. Marks Organometallics 13 1994 3755
43. See inter alia M. Vathauer, and W. Kaminsky Polymer 42 2001 4017
44. S. Beck, H.H. Brintzinger, J. Suhm, and R. Mülhaupt Macromol. Rapid Commun. 19 1998 235
45. I. Kim, and R.F. Jordan Macromolecules 29 1996 489
46. Y.-X. Chen, M.D. Rausch, and J.C.W. Chien Organometallics 13 1994 748 and references cited therein
47. J. Klosin, G.R. Roof, E.X.-Y. Chen, and K.A. Abboud Organometallics 19 2000 4684
48. M. Bochmann, and M.J. Sarsfield Organometallics 17 1998 5908
49. For recent mechanistic work in the absence of monomer, see C. Gotz, A. Rau, and J. Luft J. Mol. Catal. A 184 2002 95
50. E.X.-Y. Chen, W.J. Kruper, G. Roof, and D.R. Wilson J. Am. Chem. Soc. 123 2001 745
51. S. Feng, G.R. Roof, and E.X.-Y. Chen Organometallics 21 2002 832
52. F. Guerin, and D.W. Stephan Angew. Chem., Int. Ed. 39 2000 1298
53. F. Song, R.D. Cannon, S.J. Lancaster, and M. Bochmann J. Mol. Catal. A 218 2004 21
54. A. Al-Humydi, J.C. Garrison, W.J. Youngs, and S. Collins Organometallics 24 2005 193
55. R.A. Stapleton, B.R. Galan, S. Collins, R.S. Simons, J.C. Garrison, and W.J. Youngs J. Am. Chem. Soc. 125 2003 9246
56. M. Nele, S. Collins, M.L. Diaz, J.C. Pinto, S. Lin, and R.M. Waymouth Macromolecules 33 2000 7249
57. G. Moscardi, and L. Resconi Organometallics 20 2001 1918
58. S. Lieber, M. Prosenc, and H.H. Brintzinger Organometallics 19 2000 377
59. A.G. Carr, D.M. Dawson, M. Pett, and M. Bochmann Organometallics 18 1999 2933
60. H.V. Heijden, B. Hessen, and A.G. Orpen J. Am. Chem. Soc. 120 1998 1112
61. D.E. Richardson, N.G. Alameddin, M.F. Ryan, T. Hayes, J.R. Eyler, and A.R. Siedle J. Am. Chem. Soc. 118 1996 11244
62. A.D. Horton Organometallics 15 1996 2675
63. S. Liu, F. Liu, G. Renkes, and S.G. Shore Organometallics 20 2001 5717
64. F. Liu, J. Liu, E. Meyers, and S.G. Shore J. Am. Chem. Soc. 122 2000 6106
65. X. Yang, C.L. Stern, and T.J. Marks Angew. Chem., Int. Ed. Engl. 31 1992 1375
66. Y. Sun, R.E. Spence, W.E. Piers, M. Parvez, and G.P. Yap J. Am. Chem. Soc. 119 1997 5132
67. J. Karl, G. Erker, and R. Frochlich J. Am. Chem. Soc. 119 1997 11165
68. This complex was not structurally characterized A.D. Sadow, and T.D. Tilley Organometallics 22 2003 3577 and references cited therein
69. M. Niehues, G. Erker, G. Kehr, P. Schwab, R. Frolich, O. Blacque, and H. Berke Organometallics 21 2002 2905
70. L. Resconi, L. Cavallo, A. Fait, and F. Piemontesi Chem. Rev. 100 2000 1253
71. L. Resconi J. Mol. Catal. A 146 1999 167
72. K. Vanka, Z. Xu, and T. Ziegler Organometallics 23 2004 2900
73. T. Matsugi, S. Matsui, S. Kojoh, Y. Takagi, Y. Imoue, T. Nakano, T. Fujita, and N. Kashiwa Macromolecules 35 2002 4880
74. M. Mitani, J. Mohri, Y. Yoshida, J. Saito, S. Ishii, K. Tsuru, S. Matsui, R. Furuyama, T. Nakano, H. Tanaka, S. Kojoh, T. Matsugi, K. Norio, and T. Fujita J. Am. Chem. Soc. 124 2002 3327
75. Y. Yoshida, S. Matsui, Y. Takagi, M. Mitani, T. Nakano, H. Tanaka, N. Kashiwa, and T. Fujita Organometallics 20 2001 4793
76. S. Matsui, M. Mitani, J. Saito, Y. Tohi, H. Makio, N. Matsukawa, Y. Takagi, K. Tsuru, M. Nitabaru, T. Nakano, H. Tanaka, N. Kashiwa, and T. Fujita J. Am. Chem. Soc. 123 2001 6847
77. Y. Yoshida, S. Matsui, Y. Takagi, M. Mitani, M. Nitabaru, T. Nakano, H. Tanaka, and T. Fujita Chem. Lett. 2000 1270
78. (a) K. Vanka, Ph.D. Thesis, The University of Calgary, 2004
79. (b) K. Vanka, Z. Xu, and T. Ziegler Organometallics 24 2005 419
80. J.M. Blackwell, D.J. Morrison, and W.E. Piers Tetrahedron 58 2002 8247
81. A.B. Pangborn, M.A. Giardello, R.H. Grubbs, R.K. Rosen, and F.J. Timmers Organometallics 15 1996 1518
82. A.P. Shreve, R. Mulhaupt, W. Fultz, J. Calabrese, W. Robbins, and S.D. Ittel Organometallics 7 1988 409
83. A. Massey, and A. Park J. Organomet. Chem. 2 1964 245
84. W.J. Gauthier, J.F. Corrigan, N.J. Taylor, and S. Collins Macromolecules 28 1995 3771
85. M.L.H. Green, and N. Ishihara J. Chem. Soc., Dalton Trans. 1994 657
86. G.M. Diamond, S. Rodewald, and R.F. Jordan Organometallics 14 1995 5
87. W.A. Hermann, M.J.A. Morawietz, and T. Priemeier J. Organomet. Chem. 506 1996 351
88. A. Razavi, and U. Thewalt J. Organomet. Chem. 445 1993 111
89. C. Amman, P. Meier, and A.E. Merbach J. Magn. Reson. 46 1982 319
90. R.A. Stapleton, A. Al-Humydi, S. Collins, in preparation
91. A.M. Bravakis, L.E. Bailey, M. Pigeon, and S. Collins Macromolecules 31 1998 1000