메뉴 건너뛰기




Volumn 33, Issue 20, 2000, Pages 7249-7260

Two-state models for olefin polymerization using metallocene catalysts. 1. Application to fluxional metallocene catalyst systems

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CRYSTALLIZATION; MOLECULAR WEIGHT; MONOMERS; OLEFINS; POLYPROPYLENES;

EID: 0034300595     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma000401z     Document Type: Article
Times cited : (45)

References (38)
  • 17
    • 0006309899 scopus 로고
    • The use of a kinetic model to describe PP stereo-sequence length distributions using noninterconverting, multisite, Ziegler-Natta catalysts has been reported. De Carvalho, A. B. M.; Gloor, P. E.; Hamielec, A. E. Polymer 1990, 31, 1290.
    • (1990) Polymer , vol.31 , pp. 1290
    • De Carvalho, A.B.M.1    Gloor, P.E.2    Hamielec, A.E.3
  • 19
    • 0033740673 scopus 로고    scopus 로고
    • First-order kinetics are assumed-other kinetic orders in [M] can be treated but additional states may need to be invoked. For a review of kinetics of propylene polymerization using metallocene catalysts, see: Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F. Chem. Rev. 2000, 100, 1253-1346.
    • (2000) Chem. Rev. , vol.100 , pp. 1253-1346
    • Resconi, L.1    Cavallo, L.2    Fait, A.3    Piemontesi, F.4
  • 22
    • 33947485933 scopus 로고
    • This aspect was first discussed in the context of living polymerization - see: Coleman, B. D.; Fox, T. G. J. Am. Chem. Soc. 1963, 85, 1241.
    • (1963) J. Am. Chem. Soc. , vol.85 , pp. 1241
    • Coleman, B.D.1    Fox, T.G.2
  • 32
    • 0343144049 scopus 로고    scopus 로고
    • note
    • 18 It is important to emphasize that any catalyst which is very active and produces high MW, low-tacticity PP (i.e. soluble in the reaction medium) could produce PP with a broad MWD under similar conditions.
  • 33
    • 0342709638 scopus 로고    scopus 로고
    • Unpublished results
    • Nele, M. N. Unpublished results.
    • Nele, M.N.1
  • 38
    • 0342274463 scopus 로고    scopus 로고
    • Private communication
    • Carlson, Eric D. Private communication.
    • Carlson, E.D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.