Catalytic propene polymerization: Determination of propagation, termination, and epimerization kinetics by direct NMR observation of the (EBI)Zr(MeB(C6F5)3)propenyl catalyst species

Journal of the American Chemical Society

Volumn 125, Issue 33, 2003, Pages 9894-9895

  Sillars, Douglass R ^a   Landis, Clark R ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BORON DERIVATIVE; FLUORINE DERIVATIVE; ORGANIC COMPOUND; PROPYLENE; ZIRCONIUM DERIVATIVE;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; EPIMERIZATION; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; REACTION ANALYSIS;

ALKENES; COLD; ISOMERISM; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLIC COMPOUNDS; POLYPROPYLENES; ZIRCONIUM;

EID: 0043023447     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036393u     Document Type: Article

References (11)

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10. For a related report of Zr-polymeryl isomerization, see: Keaton, R. J.; Sita, L. R. J. Am. Chem. Soc. 2002, 124, 9070-9071.
11. For a closely related argument, see: Kraft, B. M.; Jones, W. D. J. Am. Chem. Soc. 2002, 124, 8681-8689.