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Volumn 44, Issue 13, 2005, Pages 4786-4795

Proton electroreduction catalyzed by cobaloximes: Functional models for hydrogenases

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; COBALT; COBAMAMIDE; HYDROGENASE; LIGAND; ORGANOMETALLIC COMPOUND; OXIME; PROTON; PYRIDINE; PYRIDINE DERIVATIVE; QUATERNARY AMMONIUM DERIVATIVE;

EID: 22544466699     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050167z     Document Type: Article
Times cited : (387)

References (95)
  • 1
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    • Aug.
    • Towards A Hydrogen Economy (special issue). Science 2004, 305, 13 (Aug).
    • (2004) Science , vol.305 , Issue.SPEC. ISSUE , pp. 13
  • 3
    • 23744479088 scopus 로고    scopus 로고
    • published online Feb 23, 10.1016/j.ccr.2005.01.014
    • (a) Artero, V.; Fontecave, M. Coord. Chem. Rev., published online Feb 23, 2005, 10.1016/j.ccr.2005.01.014.
    • (2005) Coord. Chem. Rev.
    • Artero, V.1    Fontecave, M.2
  • 66
    • 33044510077 scopus 로고    scopus 로고
    • distributed by the Bioanalytical Corp.
    • (a) Digisim 3.05 for Windows 95 distributed by the Bioanalytical Corp.
    • Digisim 3.05 for Windows 95
  • 75
    • 33044503702 scopus 로고    scopus 로고
    • note
    • If electrolysis is carried out in DMF, the solution turns green and the current drops after one turnover.
  • 77
    • 33044487368 scopus 로고    scopus 로고
    • note
    • 4. This was repeated twice, yielding ∼300 TON without observation of catalyst degradation.
  • 80
    • 33044508896 scopus 로고    scopus 로고
    • note
    • If the electrolysis experiment is stopped before complete consumption of the acid, the color turns back to yellow and the final UV-visible spectrum is identical with the initial one. However, if the electrolysis experiment is continued after total depletion of the acid, the current drops and a green color develops. This color can be due to an alternative decomposition pathway of the reactive species, which is not observed as long as there is enough acid in the solution.
  • 83
    • 0003768971 scopus 로고
    • Wiley: New York
    • 1/2 - 0.780(RT/nF) + (RT/2nF) ln(kRT/nFv), so that the wave shifts toward positive potentials by about 30/n mV (at 25°C) for a 10-fold increase of k (Bard, A., J.; Faulkner, L. R. Electrochemical Methods; Wiley: New York, 1980; p 452).
    • (1980) Electrochemical Methods , pp. 452
    • Bard, A.J.1    Faulkner, L.R.2
  • 85
    • 33044488230 scopus 로고    scopus 로고
    • note
    • 2 couple is likely to display the most Nerstian behavior.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.