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note
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If electrolysis is carried out in DMF, the solution turns green and the current drops after one turnover.
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76
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49549148309
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2 in MeOH yields 2-aminobutan-3-one oxime as a result of hydrogenation of dimethylglyoxime: Simándi, L. I.; Szeverényi, Z.; Budó-Záhonyi, E. Inorg. Nucl. Chem. Lett. 1975, 11, 773.
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note
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4. This was repeated twice, yielding ∼300 TON without observation of catalyst degradation.
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79
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0037237433
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-1 as estimated by DuBois and co-workers: Curtis, C. J.; Miedaner, A.; Ciancanelli, R.; Ellis, W. W.; Noll, B. C.; DuBois, M. R.; DuBois, D. L. Inorg. Chem. 2003, 42, 216.
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DuBois, D.L.7
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80
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33044508896
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note
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If the electrolysis experiment is stopped before complete consumption of the acid, the color turns back to yellow and the final UV-visible spectrum is identical with the initial one. However, if the electrolysis experiment is continued after total depletion of the acid, the current drops and a green color develops. This color can be due to an alternative decomposition pathway of the reactive species, which is not observed as long as there is enough acid in the solution.
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