Homogeneous catalysis of electrochemical hydrogen evolution by iron(0) porphyrins

Journal of the American Chemical Society

Volumn 118, Issue 16, 1996, Pages 3982-3983

  Bhugun, Iqbal ^a   Lexa, Doris ^a,b   Savéant, Jean Michel ^a  

^a UNIVERSITÉ PARIS DIDEROT   (France)

^b AIX MARSEILLE UNIVERSITÉ   (France)

Author keywords

[No Author keywords available]

Indexed keywords

PORPHYRIN DERIVATIVE;

ARTICLE; ELECTROCHEMISTRY;

EID: 0029882335     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja954326x     Document Type: Article

References (25)

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18. (c) The fact that iron(II) hydrides are easier to reduce than iron (II) σ-alkyl complexes derives from the electron-donating properties of the alkyl ligand as compared to hydrogen. This is the same reason that aldehydes are easier to reduce than ketones.
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25. (d) Bhugun, I.; Lexa, D.; Savéant, J-M., submitted for publication.