New class of diiron dithiolates related to the Fe-only hydrogenase active site: Synthesis and characterization of [Fe2(SR)2(CNME)7]2+

Inorganic Chemistry

Volumn 41, Issue 24, 2002, Pages 6193-6195

  Lawrence, Joshua D ^a   Rauchfuss, Thomas B ^a   Wilson, Scott R ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; CYANIDE; DITHIOL DERIVATIVE; FERROUS ION; HYDROGENASE; IRON COMPLEX; IRON HYDROGENASE; IRON SULFUR PROTEIN; IRON SULFUR PROTEINS; ISOCYANIC ACID DERIVATIVE; LIGAND; SULFUR DERIVATIVE;

ARTICLE; BINDING SITE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMISTRY; CONFORMATION; CRYSTALLOGRAPHY; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; GEOMETRY; OXIDATION; OXIDATION REDUCTION REACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

BINDING SITES; CATIONS; CRYSTALLOGRAPHY, X-RAY; CYANIDES; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; FERROUS COMPOUNDS; HYDROGENASE; IRON-SULFUR PROTEINS; LIGANDS; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; SULFUR COMPOUNDS;

EID: 0037010951     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic025919t     Document Type: Article

References (42)

1. Evans, D. J. J. Chem. Res., Synop. 2001, 297-303, 801-816 and references therein.
2. Li, H.; Rauchfuss, T. B. J. Am. Chem. Soc. 2002, 124, 726-727.
3. Gloaguen, F.; Lawrence, J. D.; Schmidt, M.; Wilson, S. R.; Rauchfuss, T. B. J. Am. Chem. Soc. 2001, 123, 12518-12527.
4. Lyon, E. J.; Georgakaki, I. P.; Reibenspies, J. H.; Darensbourg, M. Y. J. Am. Chem. Soc. 2001, 123, 3268-3278.
5. Razavet, M.; Le Cloirec, A.; Davies, S. C.; Hughes, D. L.; Pickett, C. J. J. Chem. Soc., Dalton Trans. 2001, 3551-3552.
6. Zhao, X.; Hsiao, Y.-M.; Lai, C.-H.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 2002, 41, 699-708.
7. Frey, M. ChemBioChem 2002, 3, 153-160.
8. Koelle, U. New J. Chem. 1992, 16, 157-169.
9. Gloaguen, F.; Lawrence, J. D.; Rauchfuss, T. B. J. Am. Chem. Soc. 2001, 123, 9476-9477.
10. Huhmann-Vincent, J.; Scott, B. L.; Kubas, G. J. Inorg. Chim. Acta 1999, 294, 240-254.
11. Kubas, G. J. Metal Dihydrogen and σ-Bond Complexes; Kluwer Academic/Plenum Publishers: New York, 2001.
12. Zhao, X.; Georgakaki, I. P.; Miller, M. L.; Mejia-Rodriguez, R.; Chiang, C.-Y.; Darensbourg, M. Y. Inorg. Chem. 2002, 41, 3917-3928. Kaasjager, V. E.; Henderson, R. K.; Bouwman, E.; Lutz, M.; Spek, A. L.; Reedijk, J. Angew. Chem. Int. Ed. 1998, 37, 1668-1670.
13. Zhao, X.; Georgakaki, I. P.; Miller, M. L.; Mejia-Rodriguez, R.; Chiang, C.-Y.; Darensbourg, M. Y. Inorg. Chem. 2002, 41, 3917-3928. Kaasjager, V. E.; Henderson, R. K.; Bouwman, E.; Lutz, M.; Spek, A. L.; Reedijk, J. Angew. Chem. Int. Ed. 1998, 37, 1668-1670.
14. Lemon, B. J.; Peters, J. W. Biochemistry 1999, 38, 12969-12973.
15. Peters, J. W.; Lanzilotta, W. N.; Lemon, B. J.; Seefeldt, L. C. Science 1998, 282, 1853-1858.
16. Nicolet, Y.; de Lacey, A. L.; Vernède, X.; Fernandez, V. M.; Hatchikian, E. C.; Fontecilla-Camps, J. C. J. Am. Chem. Soc. 2001, 123, 1596-1601.
17. Razavet, M.; Borg, S. J.; George, S. J.; Best, S. P.; Fairhurst, S. A.; Pickett, C. J. Chem. Commun. 2002, 700-701.
18. Malatesta, L.; Bonati, F. Isocyanide Complexes of Metals; Wiley & Sons: New York, 1969.
19. Treichel, P. M. Adv. Organomet. Chem. 1973, 11, 21-86.
20. Singleton, E.; Oosthuizen, H. E. Adv. Organomet. Chem. 1983, 22, 209-310.
21. Weber, L. Angew. Chem., Int. Ed. 1998, 37, 1515-1517.
22. Karlin, K. D.; Lippard, S. J. J. Am. Chem. Soc. 1976, 98, 6951-6957.
23. Patin, H.; Le Rouzic, A.; Lhadi, E. K.; Darchen, A.; Mousser, A.; Grandjean, D. J. Organomet. Chem. 1989, 375, 101-114.
24. Darchen, A.; Lhadi, E. K.; Patin, H.; Grandjean, D.; Mousser, A. J. Organomet. Chem. 1990, 385, C4-C8.
25. Barriere, F.; Evans, D. J.; Hughes, D. L.; Ibrahim, S. K.; Talarmin, J.; Pickett, C. J. J. Chem. Soc., Dalton Trans. 1999, 21, 957-964.
26. Rauchfuss, T. B.; Contakes, S. M.; Hsu, S. C. N.; Reynolds, M. A.; Wilson, S. R. J. Am. Chem. Soc. 2001, 123, 6933-6934.
27. Cooper, L.; Davies, S. C.; Dilworth, J. R.; Hughes, D. L.; Konkol, M.; Richards, R. L.; Sanders, J. R.; Sobota, P. Can. J. Chem. 2001, 79, 490-494.
28. Fe-Fe bonding in a face-sharing bitetrahedral molecule has also been observed: Henkel, G.; Chen, C. Inorg. Chem. 1993, 32, 1064-1065.
29. Haines, R. J.; de Beer, J. A.; Greatrex, R. J. Chem. Soc., Dalton Trans. 1976, 1749-1757.
30. Schultz, A. J.; Eisenberg, R. Inorg. Chem. 1973, 12, 518-525.
31. Treichel, P. M.; Crane, R. A.; Matthews, R.; Bonnin, K. R.; Powell, D. J. Organomet. Chem. 1991, 402, 233-248.
32. Arabi, M. S.; Mathieu, R.; Poilblanc, R. Inorg. Chim. Acta 1979, 34, L207-L208.
33. Taylor, N. J.; Arabi, M. S.; Mathieu, R. Inorg. Chem. 1980, 19, 1740-1742.
34. Bonnet, J. J.; Mathieu, R.; Poilblanc, R.; Ibers, J. A. J. Am. Chem. Soc. 1979, 101, 7487-7496.
35. Fauvel, K.; Mathieu, R.; Poilblanc, R. Inorg. Chem. 1976, 15, 976-978.
36. Arabi, M. S.; Mathieu, R.; Poilblanc, R. J. Organomet. Chem. 1979, 177, 199-209.
37. Savariault, J.-M.; Bonnet, J.-J.; Mathieu, R.; Galy, J. C. R. Hebd. Seances Acad. Sci., Ser. C 1977, 284, 663-665.
38. Zhao, X.; Georgakaki, I. P.; Miller, M. L.; Yarbrough, J. C.; Darensbourg, M. Y. J. Am. Chem. Soc. 2001, 123, 9710-9711.
39. Karlin, K. D.; Lewis, D. L.; Rabinowitz, H. N.; Lippard, S. J. J. Am. Chem. Soc. 1974, 96, 6519-6521.
40. Bassett, J. M.; Barker, G. K.; Green, M.; Howard, J. A. K.; Stone, F. G. A.; Wolsey, W. C. J. Chem. Soc., Dalton Trans. 1981, 219-227.
41. Adams, R. D.; Kwon, O. S.; Smith, M. D. Inorg. Chem. 2001, 40, 5322-5323.
42. Sellmann, D.; Wille, M.; Knoch, F. Inorg. Chem. 1993, 32, 2534-2543.