[Fe2(SR)2(μ-CO)(CNMe)6]2+ and analogues: A new class of diiron dithiolates as structural models for the Hoxair state of the Fe-only hydrogenase

Journal of the American Chemical Society

Volumn 126, Issue 46, 2004, Pages 15151-15160

  Boyke, Christine A ^a   Rauchfuss, Thomas B ^a   Wilson, Scott R ^a   Rohmer, Marie Madeleine ^b   Bénard, Marc ^b  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

^b UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CRYSTALLOGRAPHY; DERIVATIVES; ENZYMES; ISOMERS; MOLECULAR STRUCTURE; OXIDATION; PROBABILITY DENSITY FUNCTION; SPECTROSCOPIC ANALYSIS; VECTORS;

DENSITY FUNCTIONAL THEORY (DFT); ELECTRON BONDS; ISOMERIC FORMS; LIGANDS;

IRON COMPOUNDS;

ACETONITRILE; CARBONYL DERIVATIVE; CYANIDE; DIFERROUS DITHIOLATE; HYDROGEN; HYDROGENASE; IRON DERIVATIVE; PROPANEDITHIOLATE; THIOL DERIVATIVE; UNCLASSIFIED DRUG; FERROUS ION; IRON HYDROGENASE; IRON SULFUR PROTEIN;

ARTICLE; DENSITY FUNCTIONAL THEORY; ENZYME ACTIVE SITE; INFRARED SPECTROSCOPY; LOW TEMPERATURE; OXIDATION; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY; CHEMICAL STRUCTURE; CHEMISTRY; INFRARED SPECTROPHOTOMETRY; METABOLISM; OXIDATION REDUCTION REACTION;

CRYSTALLOGRAPHY, X-RAY; CYANIDES; FERROUS COMPOUNDS; HYDROGEN; HYDROGENASE; IRON-SULFUR PROTEINS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; SPECTROPHOTOMETRY, INFRARED; SULFHYDRYL COMPOUNDS;

EID: 9344244760     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja049050k     Document Type: Article

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