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Volumn 7, Issue 11, 2005, Pages 2193-2196

N-heterocyclic carbene catalyzed trifluoromethylation of carbonyl compounds

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALDEHYDE; CARBENOID; CARBONYL DERIVATIVE; ESTER DERIVATIVE; KETONE;

EID: 20444472366     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol050568i     Document Type: Article
Times cited : (137)

References (57)
  • 22
    • 20444435685 scopus 로고    scopus 로고
    • Jpn. Kokai Tokkyo Koho JP 071 18188 A2 19950509, 1995
    • (b) Fuchikami, T.; Hagiwara, T. Jpn. Kokai Tokkyo Koho JP 071 18188 A2 19950509, 1995.
    • Fuchikami, T.1    Hagiwara, T.2
  • 48
    • 20444487119 scopus 로고    scopus 로고
    • note
    • 3 (3 equiv). The reaction went to completion in 30 min at room temperature with either THF or DMF as the reaction solvent.
  • 52
    • 20444432895 scopus 로고    scopus 로고
    • (see ref 2j) see ref 2b,c,f
    • Enolizable carbonyl compounds can be trifluoromethylated using fluoride initiated reactions with TMSCF3 (see ref 2j). However, enolizable aldehydes were reported to present problems for some other trifluoromethylation methods (for examples, see ref 2b,c,f).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.