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Volumn 24, Issue 11, 2005, Pages 2688-2697

Sigma-bond metathesis reactions of zirconocene alkyl cations with phenylsilane

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC CYCLE; HYDROGENOLYSIS; PYRIDINES; SILANE; TRANSITION STATE;

EID: 20444447581     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049099z     Document Type: Article
Times cited : (29)

References (77)
  • 35
    • 0030583064 scopus 로고    scopus 로고
    • For σ-bond metathesis reactions of group 3 and lanthanide metal alkyl complexes with silanes that proceed via four-center transition states in which Si is α to the metal, see ref Id and: (a) Radu, N. S.; Tilley, T. D.; Rheingold, A. L. J. Organomet. Chem. 1996, 516, 41.
    • (1996) J. Organomet. Chem. , vol.516 , pp. 41
    • Radu, N.S.1    Tilley, T.D.2    Rheingold, A.L.3
  • 38
    • 20444441892 scopus 로고    scopus 로고
    • note
    • In this paper, the phrase ambient room light refers to standard fluorescent room lighting.
  • 55
    • 20444479025 scopus 로고    scopus 로고
    • note
    • 4 salt is insoluble. See ref 14a.
  • 56
    • 20444459432 scopus 로고    scopus 로고
    • note
    • + species occurs.
  • 57
    • 20444451602 scopus 로고    scopus 로고
    • note
    • 2+. We conclude that, at most, only a trace quantity of this mixed species is present in the isolated solid.
  • 59
    • 0035980296 scopus 로고    scopus 로고
    • For examples of samarium-mediated activations of Si-aryl bonds, see: (a) Castillo, I.; Tilley, T. D. J. Am. Chem. Soc. 2001, 123, 10526.
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 10526
    • Castillo, I.1    Tilley, T.D.2
  • 62
    • 20444480930 scopus 로고    scopus 로고
    • note
    • 3 reactions explains why more extensive reaction with the chlorobenzene solvent occurs.
  • 63
    • 20444488726 scopus 로고    scopus 로고
    • note
    • 3.
  • 67
    • 20444483209 scopus 로고    scopus 로고
    • note
    • 3 and catalyzes the conversion of 6 to 7.
  • 69
  • 71
    • 20444480544 scopus 로고    scopus 로고
    • note
    • 2-pyridyl products in related C-H activations (ref 2) must result from kinetic control.
  • 72
    • 20444502110 scopus 로고    scopus 로고
    • note
    • iPr-pyridine.
  • 76
    • 20444480153 scopus 로고    scopus 로고
    • note
    • 8 solution.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.