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0011417851
-
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note
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-1 for the methathesis of an alkyne into a thorium-acetylide bond, in addition to 3 kcal·mol, since no product was found. The value of 3 kcal·mol is assigned from chemoselectivity value of >99% yield from ΔG‡ = -RT ln(k).
-
-
-
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91
-
-
0011474393
-
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note
-
In the proposed catalytic cycle, an intermediate (reactive isomer of B) could also appear between A and C, which is at a rapid steady state, befor the insertion of the second alkyne.
-
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92
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0011415911
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note
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No Ellington oxidizing coupling products (RC=C-=CR) were observed.
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93
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0011459884
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note
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If the protonolysis of the alkyne is the rate-limiting step, a large number of oligomers are expected.
-
-
-
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94
-
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0011481754
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-
note
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For a full derivation of the kinetic rate expression based on the mechanism as presented in Scheme 2, see ref 28b.
-
-
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95
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0011519587
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-
note
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2 this complex exists as a dimer, see ref 3c.
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