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16
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17
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18
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0011531196
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note
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-1.
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19
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0011590276
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note
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Although the symmetry for 8 does not allow measurement of the site epimerization rate, we assume that inversion at zirconium also accompanies olefin dissociation for this cation.
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20
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0011591307
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Manuscript in preparation
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(a) Wendt, O.; Bercaw, J. E. Manuscript in preparation.
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23
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0000169278
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25
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0011529112
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note
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2 (15) (see Supporting Information). Unfortunately, the amount of 15 that was isolated precluded further study. The precise mechanism of the reaction forming 15 is unknown at this time.
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26
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0011649683
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note
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1H NMR spectrum of the olefin complex can be observed: a multiplet at 8.4 ppm and a matching set of doublets at -0.4 and 2.8 ppm. Upon warming to -50°C, all peaks corresponding to 17 disappear, but the course of the decomposition of the proposed olefin complex is not easily followed.
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28
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33845376878
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