Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and σ-bond metathesis at scandium

Journal of the American Chemical Society

Volumn 125, Issue 26, 2003, Pages 7971-7977

  Sadow, Aaron D ^a   Tilley, T Don ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROMETHYLATION;

ADDITION REACTIONS; ISOTOPES; METHANE; RATE CONSTANTS; SYNTHESIS (CHEMICAL);

CATALYSIS;

ALKENE; ALKYL GROUP; BENZENE; CYCLOPROPANE; HYDROCARBON; HYDROGEN; LIGAND; METHANE; PENTANE; PROPYLENE; SCANDIUM;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CRYSTAL STRUCTURE; ENTHALPY; LOW TEMPERATURE PROCEDURES; METHYLATION; MOLECULAR INTERACTION; RING CLOSING METATHESIS; SYNTHESIS;

EID: 0038788823     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja021341a     Document Type: Article

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