Iron-catalyzed cross-coupling of alkenyl sulfides with grignard reagents

Organic Letters

Volumn 7, Issue 7, 2005, Pages 1219-1222

  Itami, Kenichiro ^a   Higashi, Shohei ^a   Mineno, Masahiro ^a   Yoshida, Jun Ichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL GROUP; IRON; SULFIDE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CROSS COUPLING REACTION; GRIGNARD REACTION; REACTION ANALYSIS;

EID: 17444380857     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol047504c     Document Type: Article

References (79)

1. (a) Metal-catalyzed Cross-coupling Reactions; Diederich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, 1998.
2. (b) Cross-Coupling Reactions; Miyaura, N., Ed.; Topics in Current Chemistry Vol. 219; Springer: New York, 2002.
3. (a) Littke, A. F.; Fu, G. C. Angew. Chem., Int. Ed. 2002, 41, 4176.
4. (b) Cárdenas, D. J. Angew. Chem., Int. Ed. 2003, 42, 384.
5. (a) Tamura, M.; Kochi, J. K. J. Am. Chem. Soc. 1971, 93, 1487.
6. (b) Tamura, M.; Kochi, J. K. Synthesis 1971, 303.
7. (c) Tamura, M.; Kochi, J. J. Organomet. Chem. 1971, 31, 289.
8. (d) Neumann, S. M.; Kochi, J. K. J. Org. Chem. 1975, 40, 599.
9. (e) Smith, R. S.; Kochi, J. K. J. Org. Chem. 1976, 41, 502.
10. (f) Kwan, C. L.; Kochi, J. K. J. Am. Chem. Soc. 1976, 98, 4903.
11. (g) Kochi, J. K. Acc. Chem. Res. 1974, 7, 351.
12. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
13. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
14. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
15. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
16. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
17. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
18. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
19. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
20. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
21. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
22. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
23. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
24. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
25. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
26. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
27. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
28. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
29. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
30. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
31. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
32. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
33. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
34. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
35. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
36. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M. Tetrahedron Lett. 1985, 26, 1285. (p) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1987, 28, 2053. (q) Dell'Anna, M. M.; Mastrorilli, P.; Nobile, C. F.; Marchese, G.; Taurino, M. R. J. Mol. Catal. A: Chem. 2000, 161, 239. (r) Reddy, C. K.; Knochel, P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1700. Thioesters/Grignard reagents: (s) Cardellicchio, C.; Fiandanese, V.; Marchese, G.; Ronzini, L. Tetrahedron Lett. 1985, 26, 3595. Allylic phosphates/Grignard reagents: (t) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Synlett 1991, 513. (u) Yanagisawa, A.; Nomura, N.; Yamamoto, H. Tetrahedron 1994, 50, 6017. Aryl halides (triflates)/Grignard reagents: (v) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2002, 41, 609. (w) Fürstner, A.; Leitner, A.; Méndez, M.; Krause, H. J. Am. Chem. Soc. 2002, 124, 13856. (x) Quintin, J.; Franck, X.; Hocquemiller, R.; Figadère, B. Tetrahedron Lett. 2002, 43, 3547. (y) Fürstner, A.; Leitner, A. Angew. Chem., Int. Ed. 2003, 42, 308. (z) Hocek, M.; Hocková, D.; Dvřáková, H. Synthesis 2004, 889.
37. Alkenyl halides/Grignard reagents: (a) Molander, G. A.; Rahn, B. J.; Shubert, D. C.; Bonde, S. E. Tetrahedron Lett. 1983, 24, 5449. (b) Cahiez, G.; Avedissian, H. Synthesis 1998, 1199. (c) Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P. Synlett 2001, 1901. (d) Fakhfakh, M. A.; Franck, X.; Hocquemiller, R.; Figadère, B. J. Organomet. Chem. 2001, 624, 131. (e) Hölzer, B.; Hoffmann, R. W. Chem. Commun. 2003, 732. Alkenyl halides/organolithium reagents: (f) Walborsky, H. M.; Banks, R. B. J. Org. Chem. 1981, 46, 5074. Alkenyl halides/organomanganese reagents: (g) Cahiez, G.; Marquais, S. Tetrahedron Lett. 1996, 37, 1773. (h) Cahiez, G.; Marquais, S. Pure Appl. Chem. 1996, 68, 53. (i) Fürstner, A.; Brunner, H. Tetrahedron Lett. 1996, 37, 7009. Alkenyl sulfones/Grignard reagents: (j) Fabre, J. L.; Julia, M.; Verpeaux, J. N. Tetrahedron Lett. 1982, 23, 2469. (k) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 111. (l) Alvarez, E.; Cuvigny, T.; du Penhoat, C. H.; Julia, M. Tetrahedron 1988, 44, 119. Acyl halides/Grignard reagents: (m) Percival, W. C.; Wagner, R. B.; Cook, N. C. J. Am. Chem. Soc. 1953, 75, 3731. (n) Fiandanese, V.; Marchese, G.; Martina, V.; Ronzini, L. Tetrahedron Lett. 1984, 25, 4805. (o) Ritter, K.; Hanack, M.
38. (a) Nakamura, M.; Matsuo, K.; Ito, S.; Nakamura, E. J. Am. Chem. Soc. 2004, 126, 3686.
39. (b) Nagao, T.; Hayashi, T. Org. Lett. 2004, 6, 1297.
40. (c) Martin, R.; Fürstner, A. Angew. Chem., Int. Ed. 2004, 43, 3955.
41. See also: (d) Brinker, U. H.; König, L. Chem. Ber. 1983, 116, 882. (e) Nishii, Y.; Wakasugi, K.; Tanabe, Y. Synlett 1998, 67. (f) Bedford, R. B.; Bruce, D. W.; Frost, R. M.; Goodby, J. W.; Hird, M. Chem. Commun. 2004, 2822.
42. See also: (d) Brinker, U. H.; König, L. Chem. Ber. 1983, 116, 882. (e) Nishii, Y.; Wakasugi, K.; Tanabe, Y. Synlett 1998, 67. (f) Bedford, R. B.; Bruce, D. W.; Frost, R. M.; Goodby, J. W.; Hird, M. Chem. Commun. 2004, 2822.
43. See also: (d) Brinker, U. H.; König, L. Chem. Ber. 1983, 116, 882. (e) Nishii, Y.; Wakasugi, K.; Tanabe, Y. Synlett 1998, 67. (f) Bedford, R. B.; Bruce, D. W.; Frost, R. M.; Goodby, J. W.; Hird, M. Chem. Commun. 2004, 2822.
44. Itami, K.; Mineno, M.; Muraoka, N.; Yoshida, J. J. Am. Chem. Soc. 2004, 126, 11778.
45. For our related works on multisubstituted olefin synthesis, see: (a) Itami, K.; Mitsudo, K.; Kamei, T.; Koike, T.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2000, 122, 12013. (b) Itami, K.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 5600. (c) Itami, K.; Nokami, T.; Ishimura, Y.; Mitsudo, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 11577. (d) Itami, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2003, 125, 14670. (e) Itami, K.; Ushiogi, Y.; Nokami, T.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 3695. (f) Itami, K.; Tonogaki, K.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 4093.
46. For our related works on multisubstituted olefin synthesis, see: (a) Itami, K.; Mitsudo, K.; Kamei, T.; Koike, T.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2000, 122, 12013. (b) Itami, K.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 5600. (c) Itami, K.; Nokami, T.; Ishimura, Y.; Mitsudo, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 11577. (d) Itami, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2003, 125, 14670. (e) Itami, K.; Ushiogi, Y.; Nokami, T.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 3695. (f) Itami, K.; Tonogaki, K.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 4093.
47. For our related works on multisubstituted olefin synthesis, see: (a) Itami, K.; Mitsudo, K.; Kamei, T.; Koike, T.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2000, 122, 12013. (b) Itami, K.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 5600. (c) Itami, K.; Nokami, T.; Ishimura, Y.; Mitsudo, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 11577. (d) Itami, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2003, 125, 14670. (e) Itami, K.; Ushiogi, Y.; Nokami, T.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 3695. (f) Itami, K.; Tonogaki, K.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 4093.
48. For our related works on multisubstituted olefin synthesis, see: (a) Itami, K.; Mitsudo, K.; Kamei, T.; Koike, T.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2000, 122, 12013. (b) Itami, K.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 5600. (c) Itami, K.; Nokami, T.; Ishimura, Y.; Mitsudo, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 11577. (d) Itami, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2003, 125, 14670. (e) Itami, K.; Ushiogi, Y.; Nokami, T.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 3695. (f) Itami, K.; Tonogaki, K.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 4093.
49. For our related works on multisubstituted olefin synthesis, see: (a) Itami, K.; Mitsudo, K.; Kamei, T.; Koike, T.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2000, 122, 12013. (b) Itami, K.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 5600. (c) Itami, K.; Nokami, T.; Ishimura, Y.; Mitsudo, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 11577. (d) Itami, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2003, 125, 14670. (e) Itami, K.; Ushiogi, Y.; Nokami, T.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 3695. (f) Itami, K.; Tonogaki, K.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 4093.
50. For our related works on multisubstituted olefin synthesis, see: (a) Itami, K.; Mitsudo, K.; Kamei, T.; Koike, T.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2000, 122, 12013. (b) Itami, K.; Nokami, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 5600. (c) Itami, K.; Nokami, T.; Ishimura, Y.; Mitsudo, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2001, 123, 11577. (d) Itami, K.; Kamei, T.; Yoshida, J. J. Am. Chem. Soc. 2003, 125, 14670. (e) Itami, K.; Ushiogi, Y.; Nokami, T.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 3695. (f) Itami, K.; Tonogaki, K.; Ohashi, Y.; Yoshida, J. Org. Lett. 2004, 6, 4093.
51. 4w
52. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
53. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
54. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
55. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
56. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
57. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
58. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
59. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
60. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
61. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
62. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
63. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
64. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
65. There are many reports on nickel- or palladium-catalyzed cross-coupling reaction using sulfides. For early works, see: (a) Okamura, H.; Miura, M.; Takei, H. Tetrahedron Lett. 1979, 43. (b) Wenkert, E.; Ferreira, T. W.; Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637. (c) Takei, H.; Miura, M.; Sugimura, H.; Okamura, H. Tetrahedron Lett. 1979, 1447. (d) Okamura, H.; Takei, H. Tetrahedron Lett. 1979, 3425. For a review, see: (e) Luh, T.-Y.; Ni, Z.-J. Synthesis 1990, 89. For recent examples, see: (f) Tokuyama, H.; Yokoshima, S.; Yamashita, T.; Fukuyama, T. Tetrahedron Lett. 1998, 39, 3189. (g) Srogl, J.; Liu, W.; Marshall, D.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 9449. (h) Liebeskind, L. S.; Srogl, J. J. Am. Chem. Soc. 2000, 122, 11260. (i) Savarin, C.; Srogl, J. Liebeskind, L. S. Org. Lett. 2000, 2, 3229. (j) Angiolelli, M. E.; Casalnuovo, A. L.; Selby, T. P. Synlett 2000, 905. (k) Shimizu, T.; Seki, M. Tetrahedron Lett. 2002, 43, 1039. (l) Liebeskind, L. S.; Srogl, J. Org. Lett. 2002, 4, 979. (m) Alphonse, F.-A.; Suzenet, F.; Keromnes, A.; Lebret, B.; Guillaumet, G. Synlett 2002, 447. (n) Reference 6.
66. 3) afforded p-methoxystyrene (88.2 mg, 66%) as a pale yellow oil. All products listed in Table 1 exhibited spectral data in agreement with literature values.
67. Such an addition/elimination sequence has been proposed for the reaction of organocopper reagents with β-alkylthio-substituted α,β- unsaturated carbonyl compounds. (a) Coates, R. M.; Sowerby, R. L. J. Am. Chem. Soc. 1971, 93, 1027. (b) Posner, G. H.; Brunelle, D. J. J. Org. Chem. 1973, 38, 2747. (c) Posner, G. H.; Brunelle, D. J. J. Chem. Soc., Chem. Commun. 1973, 907. (d) Gammill, R. B.; Bryson, T. A. Tetrahedron Lett. 1975, 3793.
68. Such an addition/elimination sequence has been proposed for the reaction of organocopper reagents with β-alkylthio-substituted α,β- unsaturated carbonyl compounds. (a) Coates, R. M.; Sowerby, R. L. J. Am. Chem. Soc. 1971, 93, 1027. (b) Posner, G. H.; Brunelle, D. J. J. Org. Chem. 1973, 38, 2747. (c) Posner, G. H.; Brunelle, D. J. J. Chem. Soc., Chem. Commun. 1973, 907. (d) Gammill, R. B.; Bryson, T. A. Tetrahedron Lett. 1975, 3793.
69. Such an addition/elimination sequence has been proposed for the reaction of organocopper reagents with β-alkylthio-substituted α,β- unsaturated carbonyl compounds. (a) Coates, R. M.; Sowerby, R. L. J. Am. Chem. Soc. 1971, 93, 1027. (b) Posner, G. H.; Brunelle, D. J. J. Org. Chem. 1973, 38, 2747. (c) Posner, G. H.; Brunelle, D. J. J. Chem. Soc., Chem. Commun. 1973, 907. (d) Gammill, R. B.; Bryson, T. A. Tetrahedron Lett. 1975, 3793.
70. Such an addition/elimination sequence has been proposed for the reaction of organocopper reagents with β-alkylthio-substituted α,β- unsaturated carbonyl compounds. (a) Coates, R. M.; Sowerby, R. L. J. Am. Chem. Soc. 1971, 93, 1027. (b) Posner, G. H.; Brunelle, D. J. J. Org. Chem. 1973, 38, 2747. (c) Posner, G. H.; Brunelle, D. J. J. Chem. Soc., Chem. Commun. 1973, 907. (d) Gammill, R. B.; Bryson, T. A. Tetrahedron Lett. 1975, 3793.
71. There are some reports on the iron-catalyzed addition reactions (carbometalation) of organometallic reagents across alkenes and alkynes. (a) Nakamura, M.; Hirai, A.; Nakamura, E. J. Am. Chem. Soc. 2000, 122, 978. (b) Nakamura, M.; Matsuo, K.; Inoue, T.; Nakamura, E. Org. Lett. 2003, 5, 1373. (c) Hojo, M.; Murakami, Y.; Aihara, H.; Sakuragi, R.; Baba, Y.; Hosomi, A. Angew. Chem., Int. Ed. 2001, 40, 621.
72. There are some reports on the iron-catalyzed addition reactions (carbometalation) of organometallic reagents across alkenes and alkynes. (a) Nakamura, M.; Hirai, A.; Nakamura, E. J. Am. Chem. Soc. 2000, 122, 978. (b) Nakamura, M.; Matsuo, K.; Inoue, T.; Nakamura, E. Org. Lett. 2003, 5, 1373. (c) Hojo, M.; Murakami, Y.; Aihara, H.; Sakuragi, R.; Baba, Y.; Hosomi, A. Angew. Chem., Int. Ed. 2001, 40, 621.
73. There are some reports on the iron-catalyzed addition reactions (carbometalation) of organometallic reagents across alkenes and alkynes. (a) Nakamura, M.; Hirai, A.; Nakamura, E. J. Am. Chem. Soc. 2000, 122, 978. (b) Nakamura, M.; Matsuo, K.; Inoue, T.; Nakamura, E. Org. Lett. 2003, 5, 1373. (c) Hojo, M.; Murakami, Y.; Aihara, H.; Sakuragi, R.; Baba, Y.; Hosomi, A. Angew. Chem., Int. Ed. 2001, 40, 621.
74. 6
75. For reviews on directed chemical reactions: (a) Hoveyda, A. H.; Evans, D. A.; Fu, G. C. Chem. Rev. 1993, 93, 1307. (b) Beak, P.; Meyers, A. I. Acc. Chem. Res. 1986, 19, 356. (c) Snieckus, V. Chem. Rev. 1990, 90, 879. (d) Beak, P.; Basu, A.; Gallagher, D. J.; Park, Y. S.; Thayumanavan, S. Acc. Chem. Res. 1996, 29, 552. (e) Whisler, M. C.; MacNeil, S.; Snieckus, V.; Beak, P. Angew. Chem., Int. Ed. 2004, 43, 2206.
76. For reviews on directed chemical reactions: (a) Hoveyda, A. H.; Evans, D. A.; Fu, G. C. Chem. Rev. 1993, 93, 1307. (b) Beak, P.; Meyers, A. I. Acc. Chem. Res. 1986, 19, 356. (c) Snieckus, V. Chem. Rev. 1990, 90, 879. (d) Beak, P.; Basu, A.; Gallagher, D. J.; Park, Y. S.; Thayumanavan, S. Acc. Chem. Res. 1996, 29, 552. (e) Whisler, M. C.; MacNeil, S.; Snieckus, V.; Beak, P. Angew. Chem., Int. Ed. 2004, 43, 2206.
77. For reviews on directed chemical reactions: (a) Hoveyda, A. H.; Evans, D. A.; Fu, G. C. Chem. Rev. 1993, 93, 1307. (b) Beak, P.; Meyers, A. I. Acc. Chem. Res. 1986, 19, 356. (c) Snieckus, V. Chem. Rev. 1990, 90, 879. (d) Beak, P.; Basu, A.; Gallagher, D. J.; Park, Y. S.; Thayumanavan, S. Acc. Chem. Res. 1996, 29, 552. (e) Whisler, M. C.; MacNeil, S.; Snieckus, V.; Beak, P. Angew. Chem., Int. Ed. 2004, 43, 2206.
78. For reviews on directed chemical reactions: (a) Hoveyda, A. H.; Evans, D. A.; Fu, G. C. Chem. Rev. 1993, 93, 1307. (b) Beak, P.; Meyers, A. I. Acc. Chem. Res. 1986, 19, 356. (c) Snieckus, V. Chem. Rev. 1990, 90, 879. (d) Beak, P.; Basu, A.; Gallagher, D. J.; Park, Y. S.; Thayumanavan, S. Acc. Chem. Res. 1996, 29, 552. (e) Whisler, M. C.; MacNeil, S.; Snieckus, V.; Beak, P. Angew. Chem., Int. Ed. 2004, 43, 2206.
79. For reviews on directed chemical reactions: (a) Hoveyda, A. H.; Evans, D. A.; Fu, G. C. Chem. Rev. 1993, 93, 1307. (b) Beak, P.; Meyers, A. I. Acc. Chem. Res. 1986, 19, 356. (c) Snieckus, V. Chem. Rev. 1990, 90, 879. (d) Beak, P.; Basu, A.; Gallagher, D. J.; Park, Y. S.; Thayumanavan, S. Acc. Chem. Res. 1996, 29, 552. (e) Whisler, M. C.; MacNeil, S.; Snieckus, V.; Beak, P. Angew. Chem., Int. Ed. 2004, 43, 2206.