A study of the suitability of gas chromatography-electron capture detection for the analysis of deoxynivalenol in cereals

Mycotoxin Research

Volumn 16, Issue 2, 2000, Pages 73-90

  Eskola, M ^a   Boonzaaijer, G ^b   Van Osenbruggen, W A ^b   Rizzo, A ^a   Tijmensen, G ^b  

^a NATL VET AND FOOD RES INSTITUTE   (Finland)

^b TNO   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1642287411     PISSN: 01787888     EISSN: 18671632     Source Type: Journal    
DOI: 10.1007/BF02946107     Document Type: Article

References (41)

1. Prelusky DB, Rotter BA, Rotter RG (1994) Toxicology of mycotoxins in Mycotoxins in Grain Compounds other than Aflatoxin, Miller JD and Trenholm HL (Ed), Eagan Press, St. Paul, MN, pp. 359-403
2. Ueno Y (1977) Trichothecenes: overview address in Mycotoxins in Human and Animal Health, Rodricks JV, Hesseltine CW and Mehlman MA (Ed). Pathotox Publishers Inc, Park Forest South, IL pp. 189-207
3. Josephs RD, Krska R, Grasserbauer M, Broekaert JAC (1998) Determination of trichothecene mycotoxins in wheat by use of supercritical fluid extraction and high-performance liquid chromatography with diode array detection or gas chromatography with electron capture detection. J Chromatogr A 795:297-304
4. Kotal F, Holadová K, Hajšlová J, Poustka J, Radovái Z (1999) Determination of trichothecenes in cereals. J Chromatogr A 830:219-225
5. Langseth W, Clasen P-E (1992) Automation of a clean-up procedure for determination of trichothecenes in cereals using a charcoal-alumina column. J Chromatogr 603: 290-293
6. Möller TE, Gustavsson HF (1992) Determination of type A and B trichothecenes in cereals by gas chromatography with electron capture detection. J AOAC Int 75:1049-1053
7. Onji Y, Aoki Y, Tani N, Umebayashi K, Kitada Y, Dohi Y (1998) Direct analysis of several Fusarium mycotoxins in cereals by capillary gas chromatography-mass spectrometry. J Chromatogr A 815:59-65
8. Schollenberger M, Lauber U, Jara HT, Suchy S, Drocher W, Miiller H-M (1998) Determination of eight trichothecenes by gas chromatography-mass spectrometry after sample clean-up by a two-stage solid-phase extraction. J Chromatogr A 815: 123-132
9. Scott PM, Kanhere SR, Tarter EJ (1986) Determination of nivalenol and deoxynivalenol in cereals by electron-capture gas chromatography. J Assoc Off Anal Chem 69:889-893
10. Scott PM, Lau P-Y, Kanhere SR (1981) Gas chromatography with electron capture and mass spectrometric detection of deoxynivalenol in wheat and other grains. J Assoc OffAnal Chem 64:1364-1371
11. Seidel V, Lang B, Frail]ler S, Lang C, Schiller K, Filek G, Lindner W (1993) Analysis of trace levels of trichothecene mycotoxins in Austrian cereals by gas chromatography with electron capture detection. Chromatographia 37:191-201
12. Tacke BK, Casper HH (1996) Determination of deoxynivalenol in wheat, barley and malt by column cleanup and gas chromatography with electron capture detection. J AOAC Int 79:472-475
13. Tanaka T, Hasegawa A, Matsuki Y, Ishii K, Ueno Y (1985) Improved methodology for the simultaneous detection of the trichothecene mycotoxins deoxynivalenol and nivalenol in cereals. Food Addit Contam 2:125-137
14. Weingaertner J, Krska R, Praznik W, Grasserbauer M, Lew H (1997) Use of Mycosep multifunctional clean-up columns for the determination of trichothecenes in wheat by electron-capture gas chromatography. Fresenius J Anal Chem 357:1206-1210
15. Langseth W, Rundberget T (1998) Instrumental methods for determination ol; nonmacrocyclic trichothecenes in cereals, foodstuffs and cultures. J Chromatogr A 815:103-121
16. Berger U, Oehme M, Kuhn F (1999) Quantitative determination and structure elucidation of type A-and B-trichothecenes by HPLC/ion trap multiple mass spectrometry. J Agric Food Chem 47:4240-4245
17. Krska R (1998) Performance of modem sample preparation techniques in the analysis of Fusarium mycotoxins in cereals. J Chromatogr A 815:49-57
18. Malone BtL Humphrey CW, Romer TR, Richard JL (1998) One-step solidphase extraction cleanup and fluorometric analysis of deoxynivalenol in grains. J AOAC Int 81:448-452
19. Radová Z, Holadovái K, Hajšlovái J (1998) Comparison of two clean-up principles for determination of trichothecenes in grain extract. J Chromatogr A 829: 259-267
20. Razzazi-Fazeli E, Brhm J, Luf W (1999) Determination of nivalenol and deoxynivalenol in wheat using liquid chromatography-mass spectrometry with negative ion atmospheric pressure chemical ionisation. J Chromatogr A 854: 45-55
21. Schuhmacher R, Krska R, Weingaermer J, Grasserbauer M (1997) Interlaboratory comparison study for the determination of the Fusarium mycotoxins deoxynivalenol in wheat and zearalenone in maize using different methods. Fresenius J Anal Chem 359:510-515
22. Trucksess MW, Ready DE, Pender MK, Ligmond CA, Wood GE, Page SW (1996) Determination and survey of deoxynivalenol in white flour, whole wheat flour and bran. J AOAC Int 79:883-887
23. Walker F, Meier B (1998) Determination of the Fusarium mycotoxins nivalenol, deoxynivalenol, 3-acetyldeoxynivalenol and 15-O-Acetyl-4- deoxynivalenol in contaminated whole wheat flour by liquid chromatography with diode array detection and gas chromatography with electron capture detection. J AOAC Int 81:741-748
24. Cahill LM, Kruger SC, McAlice BT, Ramsey CS, Prioli R, Kohn B (1999) Quantification of deoxynivalenol in wheat using an immunoaffinity column and liquid chromatography. J Chromatogr A 859:23-28
25. Abramson D, Clear RM, Usleber E, Gessler R, Nowicki TW, Märtlbauer E (1998) Fusarium species and 8-keto-trichothecene mycotoxins in Manitoba barley. Cereal Chem 75:137-141
26. Furlong EB, Valente Soares LM (1995) Gas chromatographic method for quantitation and confirmation of trichothecenes in wheat. J AOAC Int 78: 386-390
27. Rood Jr HD, Buck WB, Swanson SP (1988) Gas chromatographic screening method for T-2 toxin, diacetoxyscirpenol, deoxynivalenol and related trichothecenes in feeds. J Assoc Off Anal Chem 71:493-498
28. Syderdaam EW, Thiel PG (1987) The simultaneous determination of diacetoxyscirpenol and T-2 toxin in fungal cultures and grain samples by capillary gas chromatography. Food Addit Contam 4:277-284
29. Pettersson H (1998) Intercomparison of trichothecene analysis and feasibility to produce certified calibrants and reference material. BCR information reference materials, EUR 18214 EN, European Commission
30. Boonzaaijer G (1999) Validatie van de bepaling van de trichothecenen DON (deoxynivalenol), nivalenol en T2-toxin in tarwe met behulp van GC-ECD. TNOprotocol DAS/PRT/720, TNO Voeding, Zeist, The Netherlands
31. Eskola M, Parikka P, Rizzo A (2000) Trichothecenes, ochratoxin A and zearalenone contamination and Fusarium infection in Finnish cereals in 1998. Food Addit Contam (accepted)
32. Bennett GA, Megalla SE, Shotwell OL (1984) Method of analysis for deoxynivalenol and zearalenone from cereal grains. J AOCS 61:1449-1451
33. Hastings DJ, Stenroos LE (1995) Determination of deoxynivalenol in barely, malt and beer by gas chromatography-mass spectrometry. J Am Soc Brew Chem 53:78-81
34. Gilbert J, Startin JR, Crews C (1985) Optimisation of conditions for the trimethylsilylation of trichothecene mycotoxins. J Chromatogr 319:376-381
35. Little JL (1999) Artifacts in trimethylsilyl derivatization reactions and ways to avoid them. J Chromatogr A 844:1-22
36. Gilbert J, Shepherd MJ, Startin JR (1983) A survey of the occurrence of the trichothecene mycotoxin deoxynivalenol (vomitoxin) in UK grown barley and in imported maize by combined gas chromatography-mass spectrometry. J Sci Food Agric 34:86-92
37. Greenhalgh R, Gilbert J, King RR, Blackwell BA, Startin JR, Shepherd MJ (1984) Synthesis, characterization and occurrence in bread and cereal products of an isomer of 4-deoxynivalenol (vomitoxin). J Agric Food Chem 32: 1416-1420
38. Vesonder R.F, Ciegler A, Rohwedder WK, Eppley R (1979) Re-examination of 1972 midwest corn for vomitoxin. Toxicon 17:658-660
39. Rizzo AF, Saari L, Lindfors E (1986) Derivatization oftrichothecenes and water treatment of their trimethylsilyl ethers in an anhydrous apolar solvent. J Chromatogr 368:381-386
40. Braithwaite A, Smith FJ (1996) Chromatographic Methods. Blackie Academic & Professional, Glasgow 559 pp
41. Mossoba MM, Adams S, Roach JAG, Trucksess MW (1996) Analysis of trichothecene mycotoxins in contaminated grains by gas chromatography/matrix isolation/fourier transform infrared spectroscopy and gas chromatography/mass spectrometry. J AOAC Int 79:1116-1123